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Consider an apparatus in which air is trapped in a small insulated container with an open bottom, and weighted with weights so that the air is slightly above neutral buoyancy.

This apparatus is placed in a closed bottle of water, shown below in State 1 with the floating apparatus.

enter image description here

Now we slightly squeeze the bottle, thus causing hydrostatic compression of the air. The slightly buoyant State 1 air then sinks to the bottom, shown in State 2 above.

I've had some arguments about whether this process is reversible or not, and I think it depends on 2 cases:

  1. If we consider the increase in hydrostatic pressure, the air gets more compressed as it sinks to the bottom. Releasing the squeeze would therefore not cause the air to spontaneously rise again. This case is irreversible.
  2. If we ignore hydrostatic pressure, then we can simply release our squeeze on the bottle and the air will expand again, thus regaining its buoyancy to float back to the top. This case is reversible.

In the case of including hydrostatic pressure, I can't seem to reconcile the irreversibility with entropy generation, however, so I doubt my intuition on this. Is there a way to show that the process is reversible or irreversible if we include hydrostatic pressure?

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  • $\begingroup$ Because the density of the object (with the compressing air) is increasing faster than the density of the water with depth, there will be some depth past which the object will sink. Getting it below that depth by temporarily increasing the pressure or by pulling it down with a rope doesn't matter. $\endgroup$ – BowlOfRed Dec 3 '18 at 23:40
  • $\begingroup$ I don't think there will be much entropy generation in the scenario you described. The air will compress and decompress rather gradually. Of course, in any real process, there will always be at least a small amount of entropy generated. $\endgroup$ – Chet Miller Dec 3 '18 at 23:46
  • $\begingroup$ @ChesterMiller I agree there shouldn't be much entropy generation. My confusion is that the process seems irreversible despite no entropy generation. If we put the bottle in a vacuum where it can expand the same amount that we compressed, the air will not rise again because it is compressed by a larger hydrostatic gravity than we initially had. Therefore, the process doesn't seem reversible since we can't bring the system back to the initial state. It seems like irreversibility without entropy generation, which is weird. $\endgroup$ – Drew Dec 4 '18 at 0:57
  • $\begingroup$ I really don't see why the system won't be able to return to close to its initial state once the squeezing is released and allowed to re-equilibrate. It seems to me essentially all the entropy generation will be manifested as a slight increase in the temperature of the tank contents. That's about it as far as I can tell. $\endgroup$ – Chet Miller Dec 4 '18 at 1:18
  • $\begingroup$ This is called a Cartesian diver. I spent many hours playing with them when I was a kid. $\endgroup$ – PM 2Ring Dec 4 '18 at 4:02
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This state of affairs can be analyzed without including entropy arguments, as follows.

Submarines deal with this problem all the time, in that if the sub is positively buoyant and is set to descend deeper under power, as it descends the pressure of the water outside the hull forces the hull to contract, decreasing its displacement and hence its buoyancy. So the deeper it get, the less buoyancy it possesses- and if it dives beyond the neutral buoyancy point, it will sink on its own even with its motors stopped. If unchecked, the sub continues down out of control until its hull gets crushed and implodes.

Alternatively, if a dived sub is trimmed into a neutral bouyancy state and then turns on its motors to drive to the surface, as it rises its hull expands, increasing its displacement and hence its buoyancy- leading to an ever-increasing rate of rise which persists even with its motors shut down. If unchecked, the sub rises faster and faster and will breach itself partway out of the water upon reaching the surface.

This means that a dived submarine is dynamically unstable. If trimmed into perfectly neutral buoyancy, a slight upwards perturbation will grow into a rise, and a slight downward perturbation will devolve into a dive.

A dived sub must therefore be driven "hands-on" at all times, with both its net buoyancy adjusted on its way down and again on its way up, and the amount of lift its diving planes generate being similarly trimmed constantly by changing their angle of attack and the sub's speed through the water.

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Not my strong suit, but...

If the container is compressed vertically instead of horizontally, the hydrostatic pressure would be reduced allowing the vessel to rise again. Once it crossed the threshold required for the compressed air to return its buoyancy, even if the squeeze was released it should continue to rise as the gas expands.

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