First assertion
If a system is already in a high temperature, adding energy, will increment the entropy in a low amount (compared with a system in a lower temperature).
Question (if assertion is right)
What if the heat is enough that let molecules breaks (activation energy), this would lead to new multiplicity (more freedom) so more entropy. It is a higher entropy grow than if the temperature were lower! that seems to be in contradiction with first assertion.
I see there is something wrong here, but I don't know where.