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AFAIK all known quantum laws are unitary (except the collapse postulate, which is dubious anyway).

Why is it important that the laws be unitary?

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3 Answers 3

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Unitary is indeed connected to symmetry; it is therefore an important organizing principle which we should look for and expect to find at some level. This does not imply that we can claim to know it will be found exactly, or always applying to every process. Maybe it will, maybe it won't. In this respect it is like parity conservation: an important concept, but not necessarily the whole story. However, unlike parity, we have, at present, no confident way to proceed with the question "if not unitary, then what?" We have only some tentative ideas of what to look for or how it might go. The idea of a stochastic contribution to fundamental dynamics is not completely ruled out. It is simply that one should not give up unitarity lightly, because it is closely connected to energy conservation and information conservation. One should require a non-unitary model to show good credentials.

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  • $\begingroup$ when you say that "The idea of a stochastic contribution to fundamental dynamics is not completely ruled out" do you mean that if unitarity was not really fundamental in physics then there would be no symmetries and chaos would rather be fundamental? @AndrewSteane $\endgroup$
    – vengaq
    Commented Apr 7, 2023 at 11:46
  • $\begingroup$ It would change the character of symmetries. A stochastic field can have exact symmetry in its probability distribution, for example, while the resulting physical behaviour only has the symmetry in some average way. $\endgroup$ Commented Apr 17, 2023 at 13:57
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Because symmetry is an important principle in physics, and it dictates unitarity (but see the end of my answer for an additional possibility). Also see my answer here on unitary time evolution.

Symmetry here means symmetry in physical laws when going from one point of view to another. As far as physics is concerned, us humans observe/measure the results of physical experiments. If you perform an experiment in two different ways, but still obtain the same result of measurement, we say that it constitutes a symmetry between the two ways.

Symmetries are the cornerstone of physics. If there were no symmetries, our universe would be very different since any two different points of view would give different results of measurement; a chaotic place to be indeed. It turns out that we are not so unlucky as there certainly are symmetries in play in our universe. Historically, it took us time to discover the presence and to appreciate the variety, pervasiveness and usefulness of symmetries in our physical laws. Variety, because there are not one but many symmetries. Pervasiveness, because seemingly different theories follow the same symmetry principles, thereby allowing us to unify them in one general framework (e.g. electricity + magnetism = electromagnetism). Usefulness, because the presence of symmetries (along with the above-mentioned unifying general framework) allows us to construct theories that are predictive: we can calculate, using our theory, what the result of an experiment would be (and then later compare it with actual measurement in order to verify the theory's validity). The presence of symmetries, in the first place, allows us to engineer a predictive theory; without symmetries, we would actually have to perform an experiment to know what its result would be, since the absence of a symmetric structure in our physical laws would preclude us from calculating anything a priori.

Now, symmetries are important and we know we have them in our universe, but then what? How do we add (or base upon them, rather) them to our theory, before actually using its consequences? That's Wigner's theorem, which says that every symmetry transformation that acts on physical states (rays), can be represented in the Hilbert space of physical states by:

a unitary and linear operator

$\qquad$ or

an anti-unitary and anti-linear operator.

(So note that you can have anti-unitary operators as well, eg. time reversal.) In the context of quantum mechanics, conservation of transition probabilities, under a transformation, constitutes a symmetry.

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  • $\begingroup$ So if unitarity was "broken" (I mean, we found the universe to be fundamentally not unitary) then all fundamental symmetries (like Poincaré, Lorentz, diffeomorphism, CPT, translational, gauge... invariances) would be broken? Is there any remote possibility that the universe could have been non-unitary? @Avantgarde $\endgroup$
    – vengaq
    Commented Apr 7, 2023 at 11:49
  • $\begingroup$ @vengaq No, unitarity is critical $\endgroup$
    – Avantgarde
    Commented Apr 7, 2023 at 12:57
  • $\begingroup$ if unitarity was "broken" (I mean, we found the universe to be fundamentally not unitary) then all fundamental symmetries (like Poincaré, Lorentz, diffeomorphism, CPT, translational, gauge... invariances) would be broken? @Avantgarde $\endgroup$
    – vengaq
    Commented Apr 7, 2023 at 20:44
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Here is another way to look at this.

You can consider unitarity as a requirement that in any process described by your model, the sum of the probabilities of all the different pathways that the process can take must be equal to one. In a crude sense (and I invite the experts to correct me if my interpretation of this is wrong) if that probability sum is less than one, it means something that should have happened did not and if the sum is greater than one, something that shouldn't have happened did. In either case this indicates that your model doesn't correctly describe the world- either there's an unphysical flaw in your model or in the manner it furnishes probabilities.

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  • $\begingroup$ If probability $>1$ it doesn't mean that something actually happened when it shouldn't; that would be impossible. Something can happen with $100\%$ certainty, at best. It doesn't make sense to say that something happened with $150\%$ certainty, and neither does it mean that something else, too, happened in addition. Probability is defined to be bounded from above by $1$ and below by $0$. If it takes any other value, it means you need to check how your theory got you that value. $\endgroup$
    – Avantgarde
    Commented Oct 21, 2018 at 22:16
  • $\begingroup$ my point was that if probability sum >1, the theory was impossible (it furnishes an impossible result) . In my mind, having a probability sum exceeding one means you included a reaction path by error; having another less than one means you omitted something. Is this an acceptable way of thinking about this? $\endgroup$ Commented Oct 21, 2018 at 23:22
  • $\begingroup$ Not always, no. Just by looking at the result that the sum of probabilities does not equal 1 does not necessarily imply that we missed or added something extra. There are cases in physics where you get negative probabilities. We have to check all these on a case-by-case basis and see wherein, exactly, the problem lies. $\endgroup$
    – Avantgarde
    Commented Oct 22, 2018 at 0:45

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