Here is how to evaluate the rotational kinematics of a rigid body from the Euler angles
$$\boldsymbol{\omega} = \hat{\imath} \dot{\Phi} + \mathrm{R}_X ( \hat{\jmath} \dot{\Theta} + \mathrm{R}_Y \hat{k} \dot{\Psi}) \tag{1} $$
Here is how to derive the above:
Consider the orientation to be defined as sequence of thre elementary rotations $$ \mathrm{R} = \mathrm{R}_X \mathrm{R}_Y \mathrm{R}_Z \tag{2}$$
where $\mathrm{R}_X = \mathrm{rot}(\hat{\imath},\,\Phi)$, $\mathrm{R}_Y = \mathrm{rot}(\hat{\jmath},\,\Theta)$ and $\mathrm{R}_Z = \mathrm{rot}(\hat{k},\,\Psi)$.
Now the derivative on a rotating frame dictates that
$$ \begin{aligned}
\dot{\mathrm{R}}_X & = (\hat{\imath} \dot{\Phi}) \times \mathrm{R}_X \\
\dot{\mathrm{R}}_Y & = (\hat{\jmath} \dot{\Theta}) \times \mathrm{R}_Y \\
\dot{\mathrm{R}}_Z & = (\hat{k} \dot{\Psi}) \times \mathrm{R}_Z
\end{aligned} $$
and
$$\dot{\mathrm{R}} = \boldsymbol{\omega} \times \mathrm{R} \tag{3} $$ which is used to derive $\boldsymbol{\omega}$, the rotational velocity of the rigid body.
Starting from the product rule on the left-hand side of (3)
$$ \dot{\mathrm{R}} = \dot{\mathrm{R}}_X\mathrm{R}_Y \mathrm{R}_Z + \mathrm{R}_X\dot{\mathrm{R}}_Y \mathrm{R}_Z + \mathrm{R}_X \mathrm{R}_Y\dot{\mathrm{R}}_Z$$
and substitute the derivatives from rotating frames to equate to the right-hand side of (3)
$$ \boldsymbol{\omega} \times \mathrm{R} = \left((\hat{\imath} \dot{\Phi}) \times \mathrm{R}_X \right) (\mathrm{R}_Y \mathrm{R}_Z) + \mathrm{R}_X \left( (\hat{\jmath} \dot{\Theta}) \times \mathrm{R}_Y \right) \mathrm{R}_Z + (\mathrm{R}_X \mathrm{R}_Y) \left( (\hat{k} \dot{\Psi}) \times \mathrm{R}_Z \right) $$
now start grouping and distribute the rotations. Note that $\mathrm{R} (a \times b) = (\mathrm{R} a) \times (\mathrm{R} b)$ is used below.
$$\begin{aligned} \boldsymbol{\omega} \times \mathrm{R} & = (\hat{\imath} \dot{\Phi}) \times \mathrm{R} + (\mathrm{R}_X \hat{\jmath} \dot{\Theta}) \times \mathrm{R} + (\mathrm{R}_X \mathrm{R}_Y \hat{k} \dot{\Psi}) \times \mathrm{R} \\
& = \left( \hat{\imath} \dot{\Phi}+\mathrm{R}_X \hat{\jmath} \dot{\Theta}+\mathrm{R}_X \mathrm{R}_Y \hat{k} \dot{\Psi} \right) \times \mathrm{R} \end{aligned} $$
or
$$ \boxed{ \boldsymbol{\omega} = \hat{\imath} \dot{\Phi}+\mathrm{R}_X \hat{\jmath} \dot{\Theta}+\mathrm{R}_X \mathrm{R}_Y \hat{k} \dot{\Psi} } $$
Using linear algebra the above is
$$\boldsymbol{\omega} = \pmatrix{1 \\ 0 \\ 0} \dot{\Phi}+\pmatrix{0 \\ \cos\Phi \\ \sin\Phi } \dot{\Theta}+ \pmatrix{ \sin\Theta \\ -\sin\Phi\cos\Theta \\ \cos\Phi \cos\Theta } \dot{\Psi} $$