Assume the potential $V$ is not just a function of position. I'm trying to compute $[V, L_i]$. This is what I have so far:
$$ [V, L_i] = [V, \epsilon_{ijk}x_jp_k] = \epsilon_{ijk}(x_j[V,p_k]+[V,x_j]p_k).$$
Now, I could also do the following; (let $i=x$)
$$[V, L_x] = [V, yp_z - zp_y] = y[V,p_z] - z[V, p_y].$$
In which case I wouldn't get the same answer as before, where I used the implicit summation convention. This bothers me, as the second term in the first calculation doens't seem to vanish, since $V$ could well depend on the momentum.
I know both expressions are correct, and I am tempted to simply assume that the potential $V$ commutes with the coordinates $x_i$, but I need to motivate that assumption.