Short answer
The moment of inertia is, by definition, the integral of the "second moment" about an axis of all the elements of mass $dm$ which compose the body. More generally, the definition of the inertia tensor $\mathbf J$, taking the center of mass to be the pivot point, is
$$\mathbf J \equiv \int_{\mathcal R} \left(\left(\mathbf \pi \cdot \mathbf \pi\right)\mathbf I - \mathbf \pi \otimes \mathbf \pi \right) \rho dv$$
where $\mathbf \pi = \mathbf x - \mathbf{\bar x}$ is the position vector of the element of mass $\rho dv$ relative to the center of mass, $\rho$ is the mass density of the body at $\mathbf x$, $dv$ is the volume the element of mass occupies, $\mathbf I$ is the identity tensor, and $\mathbf \pi \otimes \mathbf \pi$ is called the outer product of $\mathbf \pi$ and $\mathbf \pi$.
We define the moment of inertia and the inertia tensor these ways because their definitions appear in the expressions for angular momentum and angular kinetic energy as a natural consequence of generalizing Newtonian mechanics -- which only applies to point particles -- to the dynamic behavior of rigid bodies. In the most general case, the use of rotation tensors is required, but even in the simpler cases where only the definition you have provided for the moment of inertia is sufficient for the analysis of rigid-body motion, the idea of generalizing the mechanics of point particles to rigid bodies is the justification for this definition.
(For some basic information on tensors, feel free to check out this answer regarding the use of tensors in electromagnetism.)
Long answer
Most derivations for the moment of inertia of a body of mass $m$ use two assumptions
- The body in question is a continuum; in other words, the atomic structure of the body can be neglected, and the body can be decomposed into arbitrarily many, arbitrarily small mass elements $\rho dv$
- The body in question is rigid; in other words, the magnitude of the relative position vector $\mathbf \pi$ between two arbitrary mass elements remains constant under changes in the configuration of the body (e.g. rotations and translations).
The following derivation is adapted and abridged from Intermediate Dynamics for Engineers: A Unified Treatment of Newton-Euler and Lagrangian Mechanics by Oliver O'Reilly. A more complete treatment of this derivation as well as rigid body dynamics in general, including an extensive discussion on the different types of tensors used to analyze rigid-body motion, can be found in Part Three of the text.
Consider a rigid body of mass $m$ occupying a region $\mathcal R$ whose center of mass, located at $\mathbf{\bar x}$, has a velocity $\mathbf{\bar v}$. Additionally, consider an arbitrary mass element $\rho dv$ located at $\mathbf x$ on the body and moving with velocity $\mathbf v$. Assumption 2.) ensures that the mass element will not experience translational motion relative to the center of mass -- it will only experience rotational motion relative to the center of mass. This allows us to express the relative velocity of the mass element as
$$\mathbf v - \mathbf{\bar v} = \mathbf \omega \times \left(\mathbf x - \mathbf{\bar x}\right) = \mathbf \omega \times \mathbf \pi \tag{1}$$
where $\mathbf \omega$ is the angular velocity vector of the entire body -- not just the mass element $\rho dv$ -- relative to the center of mass.
From Newtonian mechanics, the angular momentum of a mass element about the center of mass, $d \mathbf H$, by definition is
$$d \mathbf H = \mathbf \pi \times \rho dv \mathbf v = \mathbf \pi \times \rho dv \left(\mathbf{\bar v} + \mathbf \omega \times \mathbf \pi \right)\tag{2}$$
Integrating $d \mathbf H$ over the entire region $\mathcal R$ gives us the total angular momentum of the body about the center of mass, $\mathbf H$,
$$\begin{align}\mathbf H & = \int_{\mathcal R} \left(\mathbf \pi \times \left(\mathbf{\bar v} + \mathbf \omega \times \mathbf \pi \right)\right) \rho dv \\
& = \int_{\mathcal R} \left(\mathbf \pi \times \mathbf{\bar v} + \mathbf \pi \times \left(\mathbf \omega \times \mathbf \pi \right)\right) \rho dv \\
& = \int_{\mathcal R} \mathbf \pi \times \mathbf{\bar v} \rho dv + \int_{\mathcal R} \mathbf \pi \times \left(\mathbf \omega \times \mathbf \pi \right) \rho dv\end{align} \tag{3}$$
Let's consider the first term on the right-hand side of (3). Since $\mathbf{\bar x}$ and $\mathbf{\bar v}$ are independent of the region integrated, we can take them outside of the integral,
$$\begin{align} \int_{\mathcal R} \mathbf \pi \times \mathbf{\bar v} \rho dv & = \int_{\mathcal R} \mathbf \pi \rho dv \times \mathbf{\bar v} \\
& = \int_{\mathcal R} \left(\mathbf x - \mathbf{\bar x}\right) \rho dv \times \mathbf{\bar v} \\
& = \left(\int_{\mathcal R} \mathbf x \rho dv - \int_{\mathcal R} \mathbf{\bar x} \rho dv\right) \times \mathbf{\bar v} \\
& = \left(\int_{\mathcal R} \mathbf x \rho dv - \mathbf{\bar x} \int_{\mathcal R} \rho dv\right) \times \mathbf{\bar v} \\
& = \left(\int_{\mathcal R} \mathbf x \rho dv - m \mathbf{\bar x}\right) \times \mathbf{\bar v} \end{align} \tag{4}$$
But the first term on the right-hand side of (4), by the definition of center of mass, is $m \mathbf{\bar x}$, and so,
$$\int_{\mathcal R} \mathbf \pi \times \mathbf{\bar v} \rho dv = \left(m \mathbf{\bar x} - m \mathbf{\bar x}\right) \times \mathbf{\bar v} = \mathbf 0 \times \mathbf{\bar v} = \mathbf 0 \tag{5}$$
Thus, from (3),
$$\begin{align}\mathbf H & = \int_{\mathcal R} \mathbf \pi \times \left(\mathbf \omega \times \mathbf \pi \right) \rho dv \\
& = \int_{\mathcal R} \left(\left(\mathbf \pi \cdot \mathbf \pi \right) \mathbf \omega - \left(\mathbf \pi \cdot \mathbf \omega \right) \mathbf \pi \right) \rho dv \end{align} \tag{6}$$
where we have used the vector product identity $\mathbf a \times (\mathbf b \times \mathbf c) = (\mathbf a \cdot \mathbf c) \mathbf b - (\mathbf a \cdot \mathbf b) \mathbf c$.
Defining the outer product between two vectors $\mathbf a$ and $\mathbf b$, denoted $\mathbf a \otimes \mathbf b$, as the operation with the property,
$$(\mathbf a \otimes \mathbf b) \cdot \mathbf c = (\mathbf c \cdot \mathbf b) \mathbf a$$
$$\mathbf c \cdot (\mathbf a \otimes \mathbf b) = (\mathbf c \cdot \mathbf a) \mathbf b \tag{7}$$
and the identity tensor $\mathbf I$ as the second-order tensor with the property that for any vector $\mathbf a$,
$$\mathbf I \mathbf a = \mathbf a \tag{8}$$
we can rewrite (6) as,
$$\begin{align}\mathbf H & = \int_{\mathcal R} \left(\left(\mathbf \pi \cdot \mathbf \pi \right) \mathbf I \mathbf \omega - \left(\mathbf \pi \otimes \mathbf \pi \right) \mathbf \omega \right) \rho dv \\
& = \int_{\mathcal R} \left(\left(\mathbf \pi \cdot \mathbf \pi \right) \mathbf I - \mathbf \pi \otimes \mathbf \pi \right) \mathbf \omega \rho dv \\
& = \left(\int_{\mathcal R} \left(\left(\mathbf \pi \cdot \mathbf \pi \right) \mathbf I - \mathbf \pi \otimes \mathbf \pi \right) \rho dv \right) \mathbf \omega \\
& = \mathbf J \mathbf \omega\end{align} \tag{9}$$
where we have defined $\mathbf J$ as given at the top of this answer. Similar derivations will yield the expected results for the angular kinetic energy of a rigid body, the value of the inertia tensor $\mathbf J_{P}$ about any arbitrary pivot point $P$, and the parallel axis theorem.