Let $C$ be the conformal algebra, cosisting of Lorentz generators $M$, translations $P$, special conformal transformations $K$ and dilatations $D$. Let $C_Q$ be the linear space spanned by elements of $C$ and some supersymmetry generators $Q^i_a$, where $a$ is a spinor index in whatever dimension we are considering and $i$ is an $R$-symmetry index. (In even dimensions there are two kinds of spinors, but we can ignore that in the arguments to follow.)
We are studying $[K_\mu,Q_a^i]$. It cannot be equal to zero. Indeed, we have the Jacobi identity,
$$
[P_\nu,[K_\mu,Q_a^i]]=[[P_\nu,K_\mu],Q_a^i]+[K_\mu,[P_\nu,Q_a^i]].
$$
If $[K_\mu,Q_a^i]=0$ then we have, since $[P_\nu,Q_a^i]=0$,
$$
0=[[P_\nu,K_\mu],Q_a^i]=-2[D\delta_{\mu\nu}-M_{\mu\nu},Q_a^i].
$$
The right hand side is non-zero, since $[D,Q^i_a]=\frac{1}{2}Q^i_a$ (this follows straightforwardly from $[Q,Q]=P$ and Jacobi identities if we assume that $Q^i_a$ has a definite scaling dimension) and $[M_{\mu\nu},Q_a^i]=-(\mathcal{M_{\mu\nu}})_a{}^b Q_b^i$, where $\mathcal{M_{\mu\nu}}$ is the matrix which furnishes the spinor representation of Lorentz group (this fact can be thought of either as definition of "$a$ is a spinor index" or as a part of SUSY algebra).
Having established that $[K_\mu,Q_a^i]\neq 0$, we can see that it cannot lie in $C_Q$. Indeed, on $C_Q$ the spectrum of $D$ consists of $+1$ (on translations $P$), $0$ (on $D$ and $M$) $-1$ (on $K$) and $\frac{1}{2}$ (on $Q$). On the other hand, we have the Jacobi identity
$$
[D,[K_\mu,Q_a^i]]=[[D,K_\mu],Q_a^i]+[K_\mu,[D,Q_a^i]]=-[K_\mu,Q_a^i]+\frac{1}{2}[K_\mu,Q_a^i]=-\frac{1}{2}[K_\mu,Q_a^i],
$$
so $D$ takes eigenvalue $-\frac{1}{2}$ on $[K_\mu,Q_a^i]$. Thus this commutator is necessarily not in $C_Q$ i.e. a "new operator".