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There seems to be something very strange about the relationship between quantum field theory and quantum mechanics. It is bothering me; perhaps somebody can help.

I'll consider a free Klein-Gordon field. In standard treatments (e.g. Peskin & Schroeder and Schwartz) the one-particle momentum eigenstates $| \vec{k} \rangle$ are normalized so that

$$ \langle \vec{p} | \vec{k} \rangle = 2 \omega_{\vec{p}} (2\pi)^3 \delta^{(3)}(\vec{p}-\vec{k}), \qquad 1 = \int \frac{d^3 p}{(2\pi)^3} \frac{1}{2 \omega_{\vec{p}}}| \vec{p} \rangle \langle \vec{p} |. $$ Now, assuming $\langle \vec{x}' | \vec{x} \rangle = \delta^{(3)}(x-x')$ as usual, it follows that $$ \langle \vec{x} | \vec{p} \rangle = \sqrt{2 \omega_{\vec{p}}} e^{i \vec{p} \cdot \vec{x}}. $$ Now, one can compute (here in the Schrodinger picture; see Schwartz 2.76 or P&S 2.42) that $$ \langle 0 | \phi(\vec{x}) | \vec{p} \rangle = e^{i \vec{p} \cdot \vec{x}}. $$ This is supposed to mean that $\phi$ creates a particle localized at position $\vec{x}$. P&S are a little cautious about the details, but Schwartz claims that the calculation implies $$ \phi(\vec{x}) |0 \rangle = | \vec{x} \rangle. $$ But this is false because $\langle \vec{x} | \vec{p} \rangle \neq e^{i \vec{p} \cdot \vec{x}}$ with the normalization conventions used. I suppose it could be true with some weird normalization of $| \vec{x} \rangle$, but I can't see what that might be (and at the very least this is not spelled out on the text).

Even if this works out, it seems extremely strange for there to be a relative normalization between the one-particle states of field theory and the states of one-particle relativistic quantum mechanics. One ought to be able to redo the correspondence to make the normalization work out, but I don't see how. (Note that the normalizations can be easily made to agree in the non-relativistic limit $\omega \approx m$, but that's besides the point. Even if fully relativistic quantum mechanics is inconsistent [as some texts claim without reference], at the very least the perturbative corrections for $v \ll 1$ should be recoverable from field theory.)

[Edit: This seems to go beyond normalization. We can get a feel for what kind of state $\phi(\vec{x})|0\rangle$ is by computing its wavefunction as a function of $\vec{x}'$, $$ \langle \vec{x}' | \phi(\vec{x}) |0 \rangle = \int \frac{d^3 p}{(2\pi)^3} \frac{1}{\sqrt{2 \omega_{\vec{p}}}} e^{i\vec{p} \cdot (\vec{x}-\vec{x}')}. $$ This wavefunction is peaked (I think divergent) at $\vec{x}'=\vec{x}$, so in some sense the particle is centered at $\vec{x}$, but it seems to be quite a stretch to say that it is at $\vec{x}$ (as the books do). I would go so far as to say the claim is incorrect, since in quantum mechanics saying the particle is at particular position means the wave function is a delta-function there. I guess the same language is used in the Heisenberg picture, when two-point functions are called amplitudes for particles to propagate from one spacetime point to another. This similarly seems false by the conventional meaning of amplitude as the overlap between two localized states. Words of wisdom would be appreciated.]

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    $\begingroup$ I edited the post. The issue does not seem to be normalization. $\endgroup$ – Sam Gralla Jul 8 '17 at 6:01
  • $\begingroup$ Well, yes, the state φ(x)|0> is not just a delocalized plane wave in the x-representation! It is a wavepacket centered at x , as would be obvious if you wrote it explicitly in the P&S superposition (2.41). You may edit/reshape your question. In a perverse way these are classical waves with quantum coefficients, here all the |p> s are in their now separate superselection sector. p and x are resolutely classical parameters. So you don't get quantum interference at this level! Using |x> eigenstates is overkill. For small p they are close to plane waves.... M.S's expression is unfortunate. $\endgroup$ – Cosmas Zachos Jul 8 '17 at 14:52
  • $\begingroup$ It is evident to me that your "as usual" normalization of <x'|x> = δ is flawed, so asymmetric from that of <p|k> with the simple, idiosyncratic normalization you have. That is the source of your quandaries. If you indulge Matt's funny definition of |x> he gives and reject your normalization, then, in P&S-speak, that state is (2.41). And its normalization is (2.50) for t=0, so then (2.52), convergent, localized, and weird. The point is... one hardly ever uses that! Experiments resolutely live in Energy-momentum space... $\endgroup$ – Cosmas Zachos Jul 8 '17 at 17:09
  • $\begingroup$ Hmm... I guess we agree that Matt's expression is unfortunate. It seems to me the whole language of "creates a particle at position x" is unfortunate, too (since the particle is delocalized). But, in any case, I now have a much better sense of what is going on. $\endgroup$ – Sam Gralla Jul 8 '17 at 19:40
  • $\begingroup$ Related 98711. $\endgroup$ – Cosmas Zachos Jul 8 '17 at 21:11
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Might as well collect my comments, most deleted, in this memo answer.

Essentially, QFT does not want you to go near position eigenstates of the style of QM. The eigenstate of the momentum operator, $|p\rangle$, is not the conventional QM one, nor does it have the same dimension. However, QFT distinctly does not encourage one to seek a fantastical position operator conjugate to the (P&S (2.33)) enumerating P operator it uses, and normalizes peculiarly. Angels should properly fear to tread there.

The corresponding “almost” localized conjugate state to this $|p\rangle$ I’ll call $$ \bbox[yellow]{|\tilde{x~}\rangle \equiv \phi(x)|0\rangle=\int \frac{d^3{\mathbf p}}{(2\pi)^3} \frac{e^{-i{\bf p\cdot x}}}{2\omega_p} |p\rangle} ~. $$

Schwartz unwisely labels this as $|x\rangle$, inviting one to confuse it with the standard QM state localized to x by a δ-function, which nobody uses, needs, or wants, on account of vexing paradoxes of the type you got. P&S wisely use the proportionality constant and leave things vague and evocative—but they failed to prevent your question! It is just the unique one-particle state centered at x, with this normalization property.

The momentum dimension of the QM $|x\rangle$ is 3/2, whereas that of $|\tilde{x~}\rangle$ is 1, the opposite of the QFT $|p\rangle$ we utilize in the lab.

Now, P&S (2.50-2.52) effectively normalize $|\tilde{x~}\rangle$, which I would rather rewrite as $$ \langle 0| \phi(x) \phi(y)|0\rangle=\langle \tilde{x~}|\tilde{y~}\rangle =\frac{m}{4\pi^2 r} K_1(mr), $$ with momentum dimension 2, alright, where $r\equiv|{\mathbf x} -{\mathbf y}|$, and $K_1$ is the ubiquitous modified Bessel (Basset), sharply peaked at the origin on the scale of the Compton wavelength 1/m.

Despite the mild singularity at the origin, $K_1(x)\to 1/x$ as $x\to 0$, it cuts off rapidly for large argument x, $\sqrt{\pi/2x} ~e^{-x}$. So, the states $|\tilde{x~}\rangle$ are not as fully localized at x as a δ-function QM spoils one to expect, but they lose all support outside 1-2 Compton wavelengths of the particle in question and are as good as localized. In the Figure of this equal-time wavepacket autocorrelation function, r on the abscissa is in Compton wavelength units:

K1/x in Compton wavelength units

Recall that scattering experiments effectively live in momentum space, detecting momenta and energies of classical objects -- BB pellets at this level. (The spacial info in the detectors is just a classical geometric means of determining angles of momenta.) The QM interference has all been taken care of already by QFT and Wick's theorem, at this stage of asymptotic states’ detection.

The states $|p\rangle$ are virtually classical: they do not communicate/interfere with each other, living as they do in disjoint superselection sectors of the Fock space, fully decohered. So the wavepacket $|\tilde{x~}\rangle$ is virtually classical, and its quantum nature is only apparent when operated upon with more quantum fields. In scattering experiments, one never gets to probe this slight, sub-fermi-size, nonlocality; but, who knows, in earliest big-bang cosmology, one might well contemplate to.

These wavepackets are the true (one-particle) conjugates of the momentum eigenstates (check!), $\langle \tilde{x~}|p\rangle=e^{i{\mathbf x} \cdot {\mathbf p} }$. But note this is merely a projection of a single p component out of a classical wavepacket—mere classical Fourier analysis!

Related 287759.

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  • $\begingroup$ This is an exercise in QFT in a nutshell, Zee. $\endgroup$ – innisfree Jul 10 '17 at 4:20
  • $\begingroup$ Yes, it is a standard finger exercise in most QFT courses, to reassure the student of decoupling at spacelike separations. The PSE link I provide is friendlier, however. Tony never steps into the qualified localization trap. $\endgroup$ – Cosmas Zachos Jul 10 '17 at 15:48
  • $\begingroup$ Thanks... I had mostly figured this out from your comments, but hopefully the detailed explanation will help others. $\endgroup$ – Sam Gralla Jul 10 '17 at 22:27
  • $\begingroup$ Anything to avoid the dreaded Reeh–Schlieder theorem.... anything! $\endgroup$ – Cosmas Zachos Jul 18 '17 at 15:59

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