I was reading this paper on qubit state preperation, and encountered an interesting type of single-qubit gate: \begin{align} U_\theta = \left(\begin{matrix} \cos\theta & \sin\theta \\ \sin\theta & -\cos\theta \end{matrix}\right) = \cos\theta\, \sigma_z + \sin\theta\, \sigma_x \end{align} and more generally, \begin{align} U = \frac{1}{\sqrt{|a|^2+|b|^2}}\left(\begin{matrix} a & b \\ b^* & -a^*\end{matrix}\right) \end{align}
I would like to try and decompose these gates as compositions of standard rotations, i.e. \begin{align} R_x(\theta) = \exp(-i\theta \sigma_x/2)\ \ ,\ \ \sigma_x = \left(\begin{matrix} 0 & 1 \\ 1 & 0 \end{matrix}\right) \\ R_y(\theta) = \exp(-i\theta \sigma_y/2)\ \ ,\ \ \sigma_y = \left(\begin{matrix} 0 & -i \\ i & 0 \end{matrix}\right) \\ R_z(\theta) = \exp(-i\theta \sigma_z/2)\ \ ,\ \ \sigma_z = \left(\begin{matrix} 1 & 0 \\ 0 & -1 \end{matrix}\right) \end{align}
However, I'm not really sure how to go about it, mostly due to the minus sign in the (2,2) matrix element. I've tried solving the simultaneous equations e.g. $R_X(\theta)R_Z(\phi) = U$ but I end up getting no solutions.