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In Dirac's Lectures on Quantum Mechanics he writes down the Hamiltonian for the free electromagnetic field:

\begin{equation} H = \int \frac{1}{4} F^{rs} F_{rs} + \frac{1}{2} \pi^r \pi^r - A_0 \pi^r{}_{,r} \, \mathrm{d}^3 x \end{equation}

(Note that Dirac uses $B$ to denote the conjugate momentum, so I have replaced it with $\pi$, which is less confusing.)

If one evaluates the first two terms, one recovers the familiar expression for the energy density of the field, namely $\frac{1}{2}(E^2 + B^2)$. The third term will eventually be seen to vanish once Gauss's law is recovered.

My question is: if we started out with the full Lagrangian which includes the interaction term $-\frac{1}{c} J^\mu A_\mu$, then what happens to this term when the Legendre transformation is performed? As far as I can tell, this term simply ends up in the result with changed sign, i.e.,

\begin{equation} H = H_m + \int \frac{1}{4} F^{rs} F_{rs} + \frac{1}{2} \pi^r \pi^r + \frac{1}{c} J^\mu A_\mu - A_0 \pi^r{}_{,r} \, \mathrm{d}^3 x \end{equation}

where $H_m$ denotes the Hamiltonian for matter particles alone. This now seems to give the wrong value of the energy density; the last term will cancel the $\rho \varphi$ term in $\frac{1}{c} J^\mu A_\mu$, but the $-\frac{1}{c} \mathbf{A} \cdot\mathbf{J}$ part will be left uncancelled. That means the Hamiltonian density will differ by $-\frac{1}{c} \mathbf{A} \cdot \mathbf{J}$ from the energy density

\begin{equation} u = u_m + \frac{1}{2}(E^2 + B^2) \end{equation}

So what part of this analysis is incorrect?

(Apologies if I got the units wrong; I am not proficient in cgs units.)

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  • $\begingroup$ Just to be clear: $\pi^r$ is the momentum canonically conjugate to what? $A^r$? $\endgroup$ Commented Oct 25, 2017 at 23:02

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The resulting Hamiltonian density depending on A.J is correct result obtained as a consequence of modifying the Lagrangian, and is fine physically. The Lagrangian contains prescribed sources J which affect the EM field and can give it energy, so it should be no surprise that definition of energy density reflects their presence.

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