The usual discrete symmetry operations in quantum mechanics i.e., C, P, and T, are representations of $\mathbb{Z}_2$. Are there examples of other discrete symmetry groups that appear in nature?
I know one answer to this is discrete rotational symmetry in crystals and quasicrystals. [Also, lattice gauge theories can have any discrete symmetry group you want, but this is not really something that appears in nature...] Other examples?