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The Debye model yields the following temperature dependence of specific heat: $$C = \frac{12\pi^4Nk_B}{5\theta_D^3} T^3 \,,$$ where $\theta_D$ is the Debye temperature.

From this answer, the argument is that a lower Debye temperature will indicate a softer material, like lead.

Qn: Does 'soft' in this case mean a smaller specific heat? If it does, I don't understand how we arrive at this conclusion from the equation above. At any particular temperature $T$, a smaller $\theta_D$ should give a larger Debye temperature, no?

Where am I going wrong?

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  • $\begingroup$ soft really means mechanically soft. $\theta_\mathrm{ D}$ is related to vibrational modes. That's why the answer you linked to talks about the speed of sound. So following that answer, Diamond has a higher Debye temperature than lead and a lower heat capacity as it is harder and lead is softer. $\endgroup$ – mikuszefski Apr 13 '17 at 12:20
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I think that the relation between the Debye Temperature $\theta_D$ and the "hardness/softness" of the material can be understood more easily if we directly look at the expression for the Debye temperature itself:

\begin{equation} \theta_D=\frac{\hbar \omega_{D}}{k_B} \end{equation}

Here $\omega_D$ is the Debye frequency. This can be thought as the "maximum frequency the solid normal modes can stand". If we keep this in mind we can write:

\begin{equation} \omega_D=\omega_{max}= v_s|\vec{k_{max}}|=\frac{2 \pi v_s}{\lambda_{min}} \end{equation}

I've used the dispersion relation for sound waves ($v_s$ is the propagation velocity of sound in the solid) and then I replaced $k_{max}=\frac{2 \pi}{\lambda_{min}}$.

At this point we can already give a preliminar answer. Debye temperature is proportional to the sound velocity in the solid. If you google it you'll find something like this

enter image description here

Harder materials have higher sound velocities. This is because they are "tighter" and they propagate oscilations faster. So we indeed arrive to the conclusion that harder materials have higher Debye Temperatures.

If you don't buy this kind of empirical demostration, let's go a bit further. We still have a $\lambda_{min}$ in our definition of $\theta_D$ that haven't been used:

\begin{equation} \theta_D=\frac{h v_s}{\lambda_{min}} \end{equation}

In general, $\lambda_{min}$ will be related to the geometry of the material lattice. However, for our simple purposes we can simply say that $\lambda_{min}$ must be proportional to the average distante between ions in the lattice. This is easy to see: a wave with a smaller $\lambda$ simply doesn't have anywhing to oscilate in between the ions. So now we see that the Debye Temperature is also inversely proportional to the separation of ions in the lattice. It is obvious then that tighter lattices (with ions closer to each other) will have higher Debye Temperatures, in agreement with our first thoughts.

Hope this helps!

P.D.: answering the other question, harder materials usually have smaller heat capacities, not the other way around.

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