Which would melt faster on the sidewalk, equal volumes of snow or ice?

Whilst walking back from class, I noticed the piled snow on the sides of the street still hadn't melted after a week despite it being sunny and generally warm $(15°C-18°C)$. "If that snow was ice, surely it would've melted away by now", I thought. I couldn't figure out what would melt faster on the sidewalk; the piled snow that was somewhat impacted, or the same volume filled by solid ice at the same temperature.

My thought-process was that the snow had pockets of air acting as very good insulators that would slow heat transfer even though the solid ice has a "bigger tank" for heat and needs more of it to fully melt. Ice is a much more solid structure though, allowing for far better heat conduction (via microscopic vibration) and has more of itself in contact with the ground. Snow is also shinier than ice, reflecting more sunlight. I know that there are several types of snow and this one is packed powder, with a crust that can support someone walking over it but crumbles if stomped on. The inner parts are powdery and the edges are coarse, crunchy and wet. How dirty the snow is also plays a part (since dirt has a much lower heat capacity than ice and absorbs radiation better).

This is a close-up of the snow.

Would replacing that volume with solid ice at the same temperature last longer than the snow ? My intuition says the snow would last longer but I don't know which contributing factor dominates.

• The answer is that it is complicated for the reasons you have identified: people who study climate (of whom I am sort-of one) spend a lot of time trying to understand this, and it depends on lots of factors such as albedo, whether it is dirty ('soot on snow' is a term of art), how packed it is, whether it has partly melted & refrozen &c &c. So I think there is no single answer to this question, I think. It's a good question though.
– user107153
Mar 21, 2017 at 22:47
• Thank you. Is there a "perfect" combination of factors (packing, amount of air, amount of soot, etc.) that would allow snow to melt definitively slower than solid ice ? Mar 21, 2017 at 23:15
• A week after snowfall, the stuff left on the side of the road is more accurately described as ice rather than snow. It's melted/refrozen several times with the day/night cycle most likely. Mar 22, 2017 at 3:10
• It is definitely closer to porous ice than it is to snow, but I wouldn't say it is more ice than snow. After all, is not the primary difference between snow and ice the crystalline, aerated structure vs solid sheets and blocks ? Mar 22, 2017 at 3:21
• @HsMjstyMstdn I don't know I'm afraid. As Joshua said, the transition between ice and packed snow is not completely well-defined in practice: glaciers and ice-sheets are usually thought of as ice, but in fact are packed snow of course.
– user107153
Mar 22, 2017 at 11:03

The density of snow is much lower than the density of ice - so the total heat of fusion needed to melt a volume of snow is much lower. That will mean the snow melts faster than the ice.

The air in the snow does lower the thermal conductivity - but that just means that the little heat from the air can melt the outer layer of snow without having to worry about the effect of snow "deeper inside".

In my experience a significant factor in snow melting is the presence of dirt - small dark particles that absorb energy from sunlight. "Clean" snow reflects much of the sun's power while clean (solid) ice will absorb a larger fraction of it. This is a factor that matters more for snow in the presence of sunlight - it doesn't affect snow in the shade where only the heat from the air plays a role- and that is what I believe you were asking about.

• But doesn't the heat get to the snow slower ? Mar 21, 2017 at 22:35
• This answer fails to address the question. Mar 21, 2017 at 23:23
• Thanks for the update. I see your point in the air pockets (although excellent insulators) not contributing to the "tank" for heat to fill up but if clean snow "wins" the radiation battle from the sun, doesn't ice "lose" the conduction battle from the ground because the snow only contacts a smaller surface and insulates itself from the ground via air pockets ? And isn't the battle from the ground more important than the air or sunlight ? Mar 21, 2017 at 23:52
• I dondon't think conduction from the ground is a major cause of melting - in my experience ice is firmly "stuck" to the ground meaning that there is insufficient heat flowing up from the ground to melt the snow. Iran I misunderstanding your point? Mar 21, 2017 at 23:54
• Compacted snow such as that shown in the OP can be much denser than freshly-fallen powder, and it's not at all obvious that it is significantly less dense than ice. Mar 22, 2017 at 13:33

Total energy absorbed by ice and snow will not deplete the Sun's energy or slow its delivery. Rate of heat transfer through the surface and through the ice and snow is the issue.

Factors to consider:

(1) A given volume of ice contains a greater number of water molecules than the same volume of snow. Sum all energy required to bring each molecule to melting point and you find greater total energy required to melt the ice than the snow, as Floris said in his answer. BUT, as the Sun's energy striking the surface is the same for both ice and snow, and will not be depleted (for practical purposes), regardless of the total amount absorbed, the rate of energy transfer to and through ice and snow becomes the important factor. For ice to melt faster than snow, more energy per unit time needs to be transferred into the ice.

(2) The surface will be at the triple point of water. Some water will melt, and some will evaporate. Water that evaporates uses energy that otherwise would be available for conduction through ice and snow. But neither sublimation nor evaporation will reduce the energy per unit time delivered by the Sun to the surface. As energy delivered per unit time will not decrease, heat of evaporation and latent heat of sublimation should not affect the rate of heat transfer into ice and snow. But the rate of evaporation will be greater per unit volume of snow than ice, as there will be greater surface per mole.

(3) Snow has greater surface area per mole than ice. But ice has greater number of moles per unit volume. Available energy per unit time is the same for both, so surface area per mole seems to me an important factor.

(4) Air convection through snow probably is insignificant, as snow is an insulator. Radiant energy delivered to and through the surface, and water convection via surface water seeping to the interior, may be the dominant methods of heat transfer into ice and snow. As snow is more porous, I expect convection via water seepage to be more rapid in snow than ice.

(5) The albedo of bare ice is 0.5, and the albedo of ice with snow is 0.9. As the albedo of ice is less than snow, a snow surface reflects more energy than ice. More radiant energy per unit time penetrates the surface of bare ice than snow.

In favor of snow melting faster: a) Greater surface area per mole for evaporation, b) Greater porosity per mole for water seepage to transfer heat to interior of snow.

In favor of ice melting faster: a) Radiant energy can penetrate the clear surface of ice directly to the interior.

I'd guess ice will melt faster on a sunny day, while snow will melt faster on a cloudy day, if (a) ambient air and ground temperatures are the same on both days, (b) relative humidity is the same on both days.

• Your 4th "drip" point seems excellent to me but is the conduction of heat from the ground into ice significant ? I do not know the calculations but in my head, that seems like a powerful way for ice to melt (assuming the heat from the ground is significant and constant) Mar 22, 2017 at 3:26
• @HsMjstyMstdn : Depending on how warm the ground is, I expect both ice and snow to sit on a thin film of water. It seems to me that rate of heat transfer from the ground would be the same for both. But heat in the ground is not unlimited like heat from the sun. It depends on the temperature gradient of the ground: nsidc.org/cryosphere/frozenground/how_fg_forms.html. The surface of the ground can lose its heat and cease to be a cause of melting. Mar 22, 2017 at 4:13
• "For practical purposes, an unlimited amount of energy per unit time (heat from the Sun) is available for transfer into both the snow and the ice" is simply false, and absurd to boot. Mar 22, 2017 at 11:34
• I think he meant an unlimited supply of constant, radiative heat energy from the sun. Mar 22, 2017 at 11:39
• @JackAidley : Total energy absorbed by ice and snow will not deplete the Sun's energy or slow its delivery. Rate of heat transfer through the surface and through the ice and snow is the issue. For ice to melt faster than snow, more energy per unit time needs to be transferred into the ice. I edited the answer. Please let me know if this doesn't make sense or is wrong. Thanks for your comment. Mar 22, 2017 at 13:26

As an experimental physicist, of course my first suggestion is to find a freezer with frost stuck to the walls and test it by cleaning it out, but other than that:

The main thing I can think of is that once surface snow melts, it can drip through and transfer heat further down. This is why you'll see melting snow that looks like towers of icicles - something dark gets blown on top of the snow, it absorbs sunlight and heats up, melting some snow around it, which then drips down and melts snow beneath and makes the chunk of dark stuff drop down and the process continues. This isn't possible in ice, especially since the chunk of stuff will end up sitting in a puddle of water that will also insulate it from the ice. I think this process, combined with the much smaller mass, will make snow melt much more quickly.

• Interesting points, although I think that patch of dirt would slide off the ice if we assume the shape of the ice to be roughly half a cylinder on its side. Mar 21, 2017 at 23:11

Ever made a snowman ? Quite easy to pick up that ball of snow for the upper body wasn't it. Can you imagine how heavy the solid ball of ice the same size would be ?

So, same volume but much more solid water. All things being equal much more heat energy required to melt a ball of ice compared to a ball of snow. Hence snow will melt faster. But all things are not equal are they, snow looks different to ice, much whiter, so if sunlight (radiation) is doing a lot of the melting then clean snow is going to absorb less heat per surface area than clean ice. Also we have conduction from the ground, a sheet of ice is in really good contact with the ground, snow less so. Can we work it out ? Maybe but its going to be complicated, need to take into account source of heat, type of heat (conduction, radiation ), reflectivity of surface and so on.

My money is on the snow going fastest for SAME volume.

• This answer actually seems to have exactly the same content as the question.
– jwg
Mar 22, 2017 at 9:01