I understand that the term "vector meson" denotes a meson particle (composite particle with a quark and an antiquark) which transforms as a vector under the Lorentz group. Since both the quark and the antiquark are Lorentz spinors, we have the tensor product
$$ \frac 12\otimes\frac 12 = 1\oplus 0\tag{1} $$
so from a group theoretic viewpoint, it makes sense to me that a meson is either a scalar or a vector.
But what's the exact difference between the $\pi$ and $\rho$ mesons? How does a scalar $\bar ud$ differ from a vector $\bar ud$? I suspect it has to do with the Clebsch-Gordan decomposition in $(1)$, so the scalar $\bar ud$'s spin state must be a superposition $\frac{1}{\sqrt{2}} \left(|\uparrow\downarrow\rangle-|\downarrow\uparrow\rangle\right)$
Is that correct so far?
If yes, then is it possible that a quark in a $\rho$ meson "flips its sign" such that the vector meson becomes a scalar meson? This would be some process like $\rho\to\pi+X$ with $X$ some other particle that must be there because of energy conservation, for example a photon.