In the definition of the Bloch sphere, one demands that $\theta \in [0, \pi]$ ans $\phi \in [0, 2\pi)$ so that any state on the Bloch sphere can be represented by
$$|\phi \rangle= \cos(\theta/2)|0 \rangle+ e^{i \phi} \sin(\theta/2)|1 \rangle.$$
But I was wondering why the representation is chosen to be like this since in my opinion the natural way to choose this representation would be
$$|\phi \rangle=\cos(\theta)|0 \rangle+ e^{i \phi} \sin(\theta)|1 \rangle,$$ with $\theta \in [0, \pi], \phi \in [0, 2\pi)$.
If one chooses this representation, you would get in trouble since for example the states $|\phi_1\rangle$ with $\theta_1=\pi/4$ and $\phi_1=0$ and $|\phi_2\rangle$ with $\theta_2=3\pi/4$ and $\phi_2=\pi$ would both lead (when neglecting an irrelevant phase) to the representation
$$|\phi_1 \rangle=|\phi_2\rangle=\frac{1}{\sqrt{2}}(|0\rangle+|1\rangle).$$
But imagine that the Axiom of Quantum mechanics, that irrelevant phases can be neglected, didn't exist, would it then be possible to choose mapping as I proposed it? Is there any mathematical constraint that I forgot about?
Are there other possibilities to choose a representation on the Bloch sphere?