For one ear alone, the sound you hear will be the sum of all sounds at that point. So there's not really such a concept as "out of phase" there... "out of phase" relative to what? If you have two speakers generating two sounds that are identical except for a 180 degree phase offset when they arrive at one ear, the perceived volume at that ear will be zero or close to it.
The story becomes a bit different when you talk about two ears. If your ears hear the same sound but it has a slight phase offset in one ear compared to the other, your brain uses this (plus a few other factors) to judge the direction to the source of the sound. E.g. a sound coming from a single point off to your side is likely to have a slightly different phase at each ear, this is part of the set of info your brain uses to figure out where the sound came from (as well as e.g. frequency filtering from the shape of your ears, amplitude differences, visual information, logical conclusions about what "makes sense" in the current situation, etc.)
So, if you're asking if one ear can distinguish between "sounds of different phase" from a single source that doesn't really make any sense.†
If you're asking if one ear can distinguish between "sounds of different phase" from multiple sources, not really, you're only really aware of the end result.
If you're asking if you can distinguish between "sounds of different phase" across both your ears, yes, you do it all the time, it's one of the things that helps you locate the source of a sound.
For the one ear, case, though, it's a lot easier to identify two sounds whose phase is changing relative to eachother, it's a common, distinctly recognizable audio effect especially with guitars, you probably recognize the sound, e.g. https://youtu.be/pvScdOldfc8?t=154.
† By "doesn't really make any sense", I actually mean: You wouldn't be able to tell unless you knew what the sound was supposed to sound like "normally" as a reference for comparison. There'd be nothing inherently identifiable about such a sound, you'd need a mental reference. If I played two identical waveforms, overlapped but with one shifted slightly, of a sound that was completely unfamiliar to you, you would not be able to identify that as any kind of "phase shifting" - it's just a waveform like any other, but if I did it to a human voice, you'd be able to tell something is odd, because you know what a voice should sound like.