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While going through de Broglie's relation in my textbook I was stuck by a derivation:

enter image description here

Here $$\ E=mc^2 $$ has been applied to photons. That confused me as I thought that mass of photon=0 but a photon does have energy. So I came across this post on SE. But this has confused me more. If the equation does not apply for photons then why have we used it here to derive the Broglie's relation?

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    $\begingroup$ Having seen a couple of your questions now: you really, really need to buy a new book. Please don't keep trying to decipher this one. $\endgroup$
    – knzhou
    Jul 10 '16 at 18:06
  • $\begingroup$ @knzhou thank you...is there any book you recomend? $\endgroup$
    – oshhh
    Jul 10 '16 at 18:08
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    $\begingroup$ Try Physics by Halliday, Resnick, and Krane. $\endgroup$
    – knzhou
    Jul 10 '16 at 18:10
  • $\begingroup$ @knzhou this is a chem book and I had to ask this ques on the chem SE but no one answers there so I asked it here. What could I refer to for chem...? $\endgroup$
    – oshhh
    Jul 10 '16 at 18:14
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    $\begingroup$ Try Chemical Principles, by Atkins. Or, try the free lecture notes and videos for the course 5.111 on MIT OCW. $\endgroup$
    – knzhou
    Jul 10 '16 at 18:17
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Okay, so first, here's another good explanation for a photon's "mass":

...the word "mass" has been used in two different ways in physics. One was the way Einstein used it in $E=mc^2,$ where mass is really just the same thing as energy (E) but measured in different units. This is the same "m" that you multiply velocity by to find momentum (p), and thus is sometimes called the inertial mass. It's also the mass that provides the source of gravitational effects. Light has this "$m$" because it has energy.$^1$

This can be briefly summarized as follows:

There are two types of mass, the type you and I think about normally, like how much mass an apple has. The second type is what light has - inertial mass. This is the sort of mass Einstein used in $E=mc^2$, that really is just the same thing as energy, but in different units.

The equation does apply for photons. A way you can see this is true is the fact that light is affected by gravity - bent by the mass of stars/planets, and trapped by black holes. It isn't "against the rules" to use the definition of mass described above.

However, as Daniel Kerr says in the comments, de Broglie's derivation is for matter, so $E = mc^2$ definitely applies. The photon part isn't really related to what the book is talking about (at the very least, it makes it unclear).

I hope this helps!

$^1$This quote is from this website.

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  • $\begingroup$ Great answer... so this mass is simply E/c^2 and has no relation with the other mass? $\endgroup$
    – oshhh
    Jul 10 '16 at 12:40
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    $\begingroup$ I believe so, yes. $\endgroup$ Jul 10 '16 at 12:40
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    $\begingroup$ Hi Heather. Photons don't react to gravity because of some hypothetical mass. In Newtonian gravity the gravitational acceleration is independent of the mass, i.e. all objects fall at the same speed, and this applies even in the limit of zero mass. In GR things are a bit more complicated but it still remains the case that a particle does not need a mass to move in a curved trajectory. So you cannot use the fact that light is bent by gravity to infer it has a mass. It does not. There is no useful sense in which a photon has a mass. $\endgroup$ Jul 10 '16 at 19:25
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    $\begingroup$ That fact requires no explanation. We are used to associating energy and momentum with massive particles from our everyday experience. But this experience lets us down in the weird world of quantum mechanics. Massless particles can have both energy and momentum because, well, that's the way QM works. If it's any consolation generations of physics students have made the same complaint about the implausibility of this, and no doubt future generations will continue to do so :-) $\endgroup$ Jul 10 '16 at 19:44
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    $\begingroup$ I think the answer is mostly fine I would just edit it with the clarification that de Broglie's derivation is for matter, so $E=mc^2$ definitely applies. The way the text describes it is misleading as they seem to be "perturbing" the photon into matter. It's not a mathematical procedure, just a semantic one. $\endgroup$ Jul 10 '16 at 20:13
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The argument in your book is heuristic, that is it presents a reasonable justification for the de Broglie wavelength but it is not a proof.

The correct expression for the de Broglie wavelength is:

$$ \lambda = \frac{h}{p} \tag{1} $$

For a massive particle in the non-relativistic limit the momentum is given by:

$$ p = mv $$

so we can write equation (1) as:

$$ \lambda = \frac{h}{mv} $$

For a photon we can use the relativistic equation linking energy and momentum:

$$ E^2 = p^2c^2 + m^2c^4 $$

And since for a photon $m=0$ this gives us $E=pc$ and therefore equation (1) becomes:

$$ \lambda = \frac{hc}{E} $$

Rearranging this gives the usual expression:

$$ E = \frac{hc}{\lambda} = h\nu $$

By comparison with a massive particle it is tempting to write the momentum of a photon as:

$$ p = mc $$

where $c$ is the photon velocity and $m$ is some hypothetical mass given by $E/c^2$. Indeed if we substitute $m=E/c^2$ in the above equation we get back the correct relativistic result:

$$ p = \frac{E}{c^2}c = \frac{E}{c} $$

But this is just numerology. The photon does not have a mass in any useful sense of the word.

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The text "any material particle … by analogy with photons" shows that the author is talking about massless photons in contrast to mass particles.

That means that his following formulations are for the best imprecise. $ E = mc^2$ applies to mass which is rest energy, and it does not apply to other types of energy. Apparently, the author wanted to say:

"if the energy of the photon was rest energy, the following formula would apply"

and his objective was the derivation of the De-Broglie equation.

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