Acceleration is defined as the time rate of change of velocity - be it in its direction or magnitude or both.
Velocity $\mathbf v$ in polar coordinates is given by:
$$\mathbf v= \dot {\mathbf r} = \dot r\mathbf{e_r} + r~\dot \theta\mathbf{e_{\theta}}\;.\tag 1$$
And then acceleration $\bf a$:
$$\mathbf a = \dot{ \mathbf v} = \left[\ddot r - r\dot \theta ^2\right]\mathbf{e_r} + \left[r\ddot \theta + 2~\dot r\dot \theta\right]\mathbf{e_\theta}\;.\tag 2$$
This is the crux of the kinematics involved in terms of polar coordinates.
Now, in circular motion, $\dot r= 0$ which leads $(2)$ to
$$\mathbf a = \dot{ \mathbf v} = - r\dot \theta ^2\mathbf{e_r} +r\ddot \theta \mathbf{e_\theta}\;.\tag {2-a}$$
The radial acceleration is the centripetal acceleration.
More precisely, in circular motion
$$\mathbf v= r\dot \theta \mathbf{e_\theta}$$
Therefore, the acceleration, is given by
$$\mathbf{a} = \frac{\mathrm d\mathbf v}{\mathrm dt}= r\frac{\mathrm d^2 \theta}{\mathrm dt^2}\mathbf{e_\theta} + \underbrace{r\frac{\mathrm d\theta}{\mathrm dt} \left(\frac{\mathrm d\mathbf {e_\theta}}{\mathrm dt}\right)}_\textrm{radial acceleration}\;.$$
So,
\begin{align}\mathbf{a_r} \equiv \textrm{centripetal acceleration} &= r\frac{\mathrm d\theta}{\mathrm dt} \left(\frac{\mathrm d\mathbf {e_\theta}}{\mathrm dt}\right)\\ &= v~(-\omega \mathbf{e_r})\;.\end{align}
Centripetal acceleration measures the time rate change of direction of the velocity vector i.e., $\mathbf{e_\theta}\;.$