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if $\frac{\sin(I)}{n}=\sin(r)$ where $n$ is the refractive index, $I$ is angle of incidence and $r$ is angle of refraction (these are relative to the normal).

How come blue light refracts at a higher angle than red light if red travels faster in glass than blue, surely $n$ for blue is larger than $n$ for red making $\sin(r)$ for red larger than that for blue, and the larger $\sin(r)$, the greater the angle (to a point)?

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You have it backward, faster speed of light in a material corresponds to less refraction, not more. In the limit that the speed of light in a material was the same as the speed of light in vacuum, there would be no refraction at all.

It can be shown that in a material the index of refraction is the speed of light in vacuum, $c$ divided by the speed of light in the material $c_m$.

$ n ={ c \over c_m} $

So, slower speed in a material corresponds to a larger index of refraction ,and higher speed to a lower index of refraction. The index of refraction is always greater than or equal to 1, because $c$, the speed of light in vacuum, is always greater than the speed in a material.

So, as you have stated, red light has a lower index of refraction than blue light since it also has a shorter wavelength, so lower index of refraction corresponds to higher speed in a material.

Now Snell's Law is stated

$${n_1 \over n_2} = {\sin \theta_2\over \sin \theta_1}$$

where the geometry is as shown:

enter image description here

So if $n_1=1.0$ and $\theta_1 = 20$ degrees we have

$n_2 =1.51$ for red light and $\theta_2 = 13.09$ degrees,

$n_2 = 1.53$ for blue light, and $\theta_2 = 12.91$ degrees.

As you can see from the diagram, a smaller value of $\theta_2$ corresponds to a larger amount of refraction because it is a larger change in angle and thus a larger change in direction of the incident light.

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  • $\begingroup$ yes, but mathematically, $\frac{Sin(I)}{n}$, if n is smaller, than sin(r) must be bigger $\endgroup$
    – Think
    May 22 '16 at 20:42
  • $\begingroup$ suppose white light comes in at an angle of 20 degrees to normal, and the refractive index of red and blue light in glass is 1.51 and 1.53, plug these in and you get red comes out at 13.1 degrees and blue 12.92 degrees, red is on the wrong side , $\endgroup$
    – Think
    May 22 '16 at 20:53
  • $\begingroup$ A smaller value of the refraction angle corresponds to a larger change in angle and thus larger refraction because of the way the angles are defined; please see the edits. $\endgroup$
    – paisanco
    May 22 '16 at 21:27
  • $\begingroup$ why red and blue have different indices of refraction if they travel at the same speed in the same medium? $\endgroup$ Nov 11 '20 at 15:51
  • $\begingroup$ They don't travel at the same speed in a refractive medium. $\endgroup$
    – paisanco
    Nov 21 '20 at 15:11
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If the question is about why red and blue light refract at different angles, this is because the refractive index, $n$ for many materials depend upon the frequency of light and they are referred to as dispersive. More often, the variation is given in terms of the wavelength ($\lambda$) and in the optics industry people quote the refractive index for the Helium d line ($\lambda = 587.6 nm$), and for the Mercury e line ($\lambda = 546.1 nm$), and a few other properties at other wavelengths, see Kaye and Laby.

The reason why the refractive index depends on frequency is related to the atomic structure of matter.

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