In the Weyl/chiral basis, the four components of the Dirac spinor represent left-chirality spin up, left-chirality spin down, right-chirality spin up, and right-chirality spin down, respectively. When solving the Dirac equation for particles at rest, we find that positive-frequency solutions have polarization $$u_s(p_0) \propto \begin{pmatrix} \xi \\ \xi \end{pmatrix}$$ while negative-frequency solutions, interpreted as positrons, have polarization $$v_s(p_0) \propto \begin{pmatrix} \xi \\ -\xi \end{pmatrix}.$$ This makes sense: a spin up positive-frequency electron, for example, is a superposition of the left-chirality spin up and right-chirality spin up components, because the mass term mixes up the chiralities.
I'm confused about what a state of definite chirality is. A spinor at rest with definite left chirality would look like $$\begin{pmatrix} \xi \\ 0 \end{pmatrix}$$ which is a superposition of the positive-frequency and negative-frequency solutions! This seems to imply that there's no such thing as a right-chiral electron; you have to have a superposition of electron and positron. This has to be wrong, because people talk about left chirality electrons all the time; for example, they are produced in beta decay. Where did I mess up?