Edit after providing the plot: Please note, that the simple model prediction of harmonics frequency position does not say anything about its strength in actual sound. It is typical feature of brass instruments in middle and lower registers that the fundamental frequency is not the strongest.
Original answer: I am sorry guys, but that's well-known and studied phenomena (that's for the comments). In fact, the question is too broad to be answered simply without examinating the concrete recording, but let me here give some notes on why it could be like that.
- Resonant frequencies of the waveguides don't have to be strictly harmonic. The key equation for simple understanding is the Webster equation for acoustic pressure dealing with the 1D waveguide along the $x$ with cross-section area $S(x)$:
$$
\frac{\partial^2 p}{\partial x^2} + \frac{\partial (\ln S(x))}{\partial x}\frac{\partial p}{\partial x}+ k^2x=0$$
Apparently, for a cylindrival duct the middle term is zero and we would have simple LHO equation.
And the mouthpiece cavity give the significant compliant element to the system. Other distortion of the harmonic behavior are termoviscous wall losses.
In the frequency domain you can see the reflections from instrument discontinuities. Typically the frequency corresponding to the first open tonehole $\lambda$ and the frequency of the whole instrument $\lambda$ as well.
There are points on the instrument with so constricted cross section that the mean flow of the breath is not negligibly small. In short: bye, the linear acoustics. We must the solve the complete Navier-Stokes eq. or at least use Burger's equation. Generally, in driven non-linear systems there could be resonances on subharmonics.
The driving of the system is nonlinear as well.
There is much of uncertainty when it comes to feedback loop of oscillator-resonator in these cases.
For the future reference I strongly recommend you The Physics of Musical Instruments by Fletcher and Rossing.