How is it possible that it can get hotter in the car than it is outside? The Law of Thermodynamics says that two bodies will eventually have equal temperatures. How is it possible that when you leave your car in the sun, it gets hotter in the car than it is outside? Why isn’t the car at the same temperature as the outside, as it should be according to the Law?
 A: The air has very low thermal conductivity and capacity, in most cases outside, the main contributor to thermal exchange (and thus perception of temperature) is radiation (Stefan's law, every object is radiating light all across the spectrum, with colder bodies giving most of it in infrared, hotter is more visible red (coal embers, hot iron), then yellow, white, bluish white when it gets hotter). In this case, the car is receiving high energy flux from the sun (absorbing most of it), so it's heating very quickly. It's like sitting near the fire - the air between you and the fire is cold, but the fire can still burn you.
Thermodynamically speaking, the car is exposed to the outside air (weakly coupled, slow transfer), the hot ground, the sky (at radiative temperature usually lower than the ambient air, possibly sub zero, if not overcast), and the sun at ~6000K temperature (strong influx, but only from a very specific direction). So you have (sun thermal radiation) + (a very little sky radiation) - (radiative losses of the car) - (conduction, convection through the air). On a sunny day, the temperature gets quite high, before the losses overcome the influx.
Radiative exchange is more important than most people realize. You know how in the winter, you may need a sweater indoors at 25 degrees, but in the summer, a T-shirt at 18 degrees is enough? That's because hot air doesn't help if the walls are cold and don't give that much thermal radiation. Similarly, a sunny day in winter is very cold because instead of relatively warm clouds, you have a "transparent" sky that gives almost no thermal radiation. That's actually the only way the earth is cooling down (and it's substantial, just see how quickly the temperature goes down when the sun sets). On a cold winter night, the surface can cool below the air temperature just because of the radiative losses, and you can actually freeze water on a reflective mirror below the open sky even if the ambient temperature is >0.
So, to conclude... for every object you are calculating the temperature balance for, you have to consider all the objects it's in thermal contact with. That's not just physical contact, every object that is in the line of sight is exchanging the heat via radiation (and in air, that's more important than the direct contact with air). Even in vacuum, where direct exchange is not possible, every object will eventually reach the average temperature of the objects all around it (with objects that take up more angular area contributing more).
That's actually how you can calculate the temperature of the sun just by measuring its size in the sky.
Let's see... the sun has angular diameter on the sky approximately half a degree. That means that out of full $4\pi$ spherical area of the entire sky around the earth, it takes up $\pi (0.5 \pi /180)^2$ (the earth is losing heat all around into $4\pi$, but receiving only from the sun). The Stefan's law states that the thermal flux goes as $T^4$, so the earth temperature will be the average $T^4$ of the sky, so
$$T_E^4 = T_S^4 \frac{\pi (0.25\pi/180)^2}{4\pi}=4.76\times 10^{-6} T_S^4$$
If the average temperature of the Earth is $290K$ (give or take), then the surface of the sun is $T_S\approx T_E/(4.76\times 10^{-6})^{1/4} \approx 6200K$. Quite impressive, considering we didn't need any numerical input or natural constants, except for the angular diameter of the sun, which we can measure with a thumb of a stretched out hand.
Maybe I went a bit off topic, but I hope it made things more clear.
A: Perhaps because of the same reasons as the warming of greenhouses? If the windows are uncovered the sunlight increase the energy inside, by isolating the warm air inside the structure so that heat is not lost by convection. [From Wikipedia]
A: 
Law of Thermodynamics says that two bodies eventually will have equal temperatures.

That is not an absolute Law. There are conditions, and one of those conditions involves the energy input to the bodies.  If this Law was absolute, then the Sun would be at the same temperature as the universe, about 2.7 K, because the universe is much larger than the Sun.  But the Sun has an internal energy converter/source which raises its local temperature.
The interior of a closed car in the sunlight will be higher because of a greenhouse effect. The glass of the car is transparent to the visible light, so that energy is absorbed by the interior of the car (the seats, dashboard, and floor) increasing their temperature.  Those items then emit infrared radiation and the glass is fairly opaque to that radiation and the energy stays in the car. So more energy comes in the glass than is escaping out of the glass.
Because the trunk/boot doesn't have a glass opening to let radiation in, it will generally stay quite a bit cooler than the passenger compartment. Whatever radiation the trunk lid gets is reflected and radiated back out fairly efficiently. That's not to say it doesn't get hot, but it doesn't get to the same as the passenger compartment.
A: While respecting the other good and thoughrough answers, I feel I can give you a simple explanation to your exact question.
As you mention in your question, two bodies eventually will have equal temperatures when in thermal contact. "Eventually" is the key. If one body's temperature is raised, the bodies will eventually find a new equilibrium temperature.
But this law doesn't prevent the rise in temperature of one body by an external source. It only says what happens from then on. As long as energy is constantly added, this temperature equality that you seek is never reached.


*

*The 1st law of thermodynamics is the law of energy conservation which explains the temperature rise.


$$\Delta U=Q-W$$
The Sun adds heat $Q$ to the car through radiation. No work is done $W=0$. Thus, internal energy $U$ must rise (corresponding to a rise in temperature).
The final steady temperature that the car reaches at a sunny day will both depend on the heat exchange with the outside air and on the incoming (as well as outgoing) radiation. All this balances at some point, by the temperature rising until heat leaving the car every second equals heat into the car every second. The temperature will not be constant until this equilibrium state is reached.
