SECTION A : Free fall of roller coaster into circular motion (kinetics)
Suppose that the roller coaster, called from now on "particle", is at rest at point A ($\:\upsilon_{A}=0\:$) and starts free falling till point B where it starts its circular motion. Well-known is that at B the speed is $\:\upsilon_{B}=\sqrt{2gh}\:$ under the assumption of no energy loss (zero air resistance etc).
Now, if the meaning of $\:g$-force in present case is the acceleration caused by the "pushing up" force $\:\mathbf{T}\:$ in $\:g \:$ units, then we must determine the magnitude $\:T=\Vert\mathbf{T}\Vert \:$ and by this : $\:g$-force =$\: T/mg\:$.
As shown in above Figure, the force $\:\mathbf{T}\:$ is normal to the circular orbit with the assumption of no friction.
If $\:\mathbf{W}\:$ is the weight of the particle and $\:\mathbf{a}\:$ its acceleration then :
\begin{equation}
\mathbf{T} + \mathbf{W}= m\mathbf{a}
\tag{A-01}
\end{equation}
It's convenient to use the $\:\left(r,\theta \right)\:$ coordinates. The expression of $\:\mathbf{a}\:$ as proved in SECTION B, equation (B-13), is
\begin{equation}
\mathbf{a}=\underbrace{\left(-r\dot{\theta}^2\right)\mathbf{e}_{r}}_{centripetal}+\underbrace{\left(r\ddot{\theta}\right)\mathbf{e}_{\theta}}_{orbital}
=\mathbf{a}_{r}+\mathbf{a}_{\theta}
\tag{A-02}
\end{equation}
So the analysis of (A-01) in $\:\mathbf{e}_{r}\:$ and $\:\mathbf{e}_{\theta}\:$ components is respectively
\begin{align}
\left( \mathbf{T} + \mathbf{W}\right)\circ\mathbf{e}_{r} &= m\mathbf{a}_{r}\: \Longrightarrow \: -T + mg\sin\theta =- mr\dot{\theta}^2
\tag{A-03a}\\
\left( \mathbf{T} + \mathbf{W}\right)\circ\mathbf{e}_{\theta} &= m\mathbf{a}_{\theta}\: \Longrightarrow \: mg\cos\theta =mr\ddot{\theta}
\tag{A-03b}\\
\end{align}
Only equation (A-03a) is important here since
\begin{equation}
T= m\;r\dot{\theta}^2 + m\;g\sin\theta
\tag{A-04}
\end{equation}
To find an expression for $\:\dot{\theta}\:$ we use equation (B-09)
\begin{equation}
\dot{\theta}=\dfrac{\upsilon}{r}
\tag{A-05}
\end{equation}
since in this case and at any instant $\:t\:$ the motion is counter-clockwise ($\:\dot{\theta}> 0\:$).
The magnitude $\:\upsilon \:$ at any point P on the circular orbit is determined from the energy conservation under the assumption of no energy loss (zero air resistance, zero friction on the track etc):
\begin{equation}
\dfrac{1}{2}m \Delta \upsilon^{2} + mg\Delta y = 0\:\Longrightarrow \: \dfrac{1}{2}m \left( \upsilon^{2}-\upsilon_{A}^{2}\right)=mg\left(h+r\sin\theta\right)
\tag{A-06}
\end{equation}
so (since $\:\upsilon_{A}=0\:$)
\begin{equation}
\upsilon=\sqrt{2g\left(h+r\sin\theta\right)}
\tag{A-07}
\end{equation}
and
\begin{equation}
r\dot{\theta}^2=\dfrac{2g\left(h+r\sin\theta\right)}{r}
\tag{A-08}
\end{equation}
Inserting above expression in (A-04) yields
\begin{equation}
T= mg\left( \dfrac{2h}{r}+3\sin\theta\right)
\tag{A-09}
\end{equation}
Finally
\begin{equation}
\text{$g$-force}=\dfrac{T}{mg} = \dfrac{2h}{r}+3\sin\theta
\tag{A-10}
\end{equation}
Note : In above Figure under scale the ratio $\:\dfrac{h}{r}\:$, the position P (that is $\:\sin\theta\:$) and the resulting $g$-force are as follow
\begin{equation}
\dfrac{h}{r}=0.40 \:,\quad \sin\theta =0.60 \:\Longrightarrow \: \text{$g$-force}=2.60
\tag{A-11}
\end{equation}
SECTION B : Kinematics of a Particle in Circular Motion
The following analysis concerns the kinematics of a particle in plane circular motion exclusively. It's a special case of a plane curvilinear motion which in its turn is special case between curvilinear motions in space.
The motion of a particle is given by the vector function $\mathbf{r}\left(t\right)$, that is by its position in time $\:t \:$. The velocity vector $\mathbf{v}\left(t\right)$ is the rate of change in time of this position vector
\begin{equation}
\mathbf{v}\left(t\right)\equiv \dfrac{d\mathbf{r}}{dt}= \dot{\mathbf{r}}
\tag{B-01}
\end{equation}
We'll use one upper dot or two upper dots for the 1st or 2nd derivative with respect to $\:t\:$, for example
\begin{equation}
\dot{\mathbf{r}}\equiv \dfrac{d\mathbf{r}}{dt}\;, \quad \dot{\theta}\equiv \dfrac{d\theta}{dt}\;, \quad \ddot{\theta}\equiv \dfrac{d^{2}\theta}{dt^{2}}
\tag{B-02}
\end{equation}
Now, let a system of coordinates $\:\left(x,y\right)\:$ in the plane as in above Figure and $\:\mathbf{i},\mathbf{j}\:$ the unit basic vectors along axis $\:Ox,Oy\:$ respectively. For plane circular motion the position vector $\mathbf{r}\left(t\right)$ of the particle may be expressed as follows :
\begin{equation}
\mathbf{r}\left(t\right)= \left[r \cos \theta \left(t\right)\right]\mathbf{i}+\left[r \sin \theta \left(t\right)\right]\mathbf{j}
\tag{B-03}
\end{equation}
Note that all quantities as position vector $\:\mathbf{r}\:$, velocity vector $\:\mathbf{v}\:$, acceleration vector $\:\mathbf{a}\:$, angle $\:\theta\:$ and as we see bellow the unit vectors $\:\mathbf{e}_{r},\mathbf{e}_{\theta}\:$ are functions of time and so it's convenient to omit $\:t\:$. The magnitude $\:r=\Vert\mathbf{r}\Vert\:$ of the position vector is of course constant in time.
So (B-03) yields
\begin{equation}
\mathbf{r}= r\left[\left(\cos\theta\right)\mathbf{i}+ \left(\sin\theta\right)\mathbf{j}\right]= r\mathbf{e}_{r}
\tag{B-04}
\end{equation}
where by definition
\begin{equation}
\mathbf{e}_{r} \equiv \left(\cos\theta\right)\mathbf{i}+ \left(\sin\theta\right)\mathbf{j}
\tag{B-05}
\end{equation}
is a unit vector along $\:\mathbf{r} \:$, as in Figure.
The velocity vector is
\begin{equation}
\mathbf{v}=\dfrac{d\mathbf{r}}{dt}= \dot{\mathbf{r}}=r\dot{\theta}\left[\left(-\sin\theta\right)\mathbf{i}+ \left(\cos\theta\right)\mathbf{j}\right]= r\dot{\theta}\mathbf{e}_{\theta}
\tag{B-06}
\end{equation}
where by definition
\begin{equation}
\mathbf{e}_{\theta} \equiv \left(-\sin\theta\right)\mathbf{i}+ \left(\cos\theta\right)\mathbf{j}
\tag{B-07}
\end{equation}
is a unit vector tangent to the circle and normal to $\:\mathbf{r} \:$, as in Figure.
Note that :
(a) The quantity $\:\dot{\theta}\:$ is essentially the instantaneous angular velocity
\begin{equation}
\dot{\theta}\equiv \dfrac{d\theta}{dt}=\omega\left(t\right)
\tag{B-08}
\end{equation}
If $\:\dot{\theta}=\omega_{o}=\text{constant}$, then we have uniform circular motion.
(b) from (B-06) for the magnitude $\:\upsilon\:$ of the velocity $\:\mathbf{v} \:$
\begin{equation}
\upsilon =r\vert\dot{\theta}\vert=r\vert\omega\vert
\tag{B-09}
\end{equation}
where $\:\omega=\dot{\theta}> 0\:$ ($\:<0\:$) if the particle moves instantly counter-clockwise (clockwise).
(c) as a general rule, if a variable vector $\:\mathbf{w}\left(\lambda\right)\:$, where $\:\lambda \:$ a real parameter, has constant norm, then its 1st derivative is always normal to it
\begin{equation}
\Vert\mathbf{w}\Vert ^{2}=\text{const}\rightarrow \mathbf{w}\circ \mathbf{w}=\text{const}\rightarrow \dfrac{d\left( \mathbf{w}\circ \mathbf{w}\right)}{d\lambda}=0\rightarrow \left( \mathbf{w}\circ \dfrac{d\mathbf{w}}{d\lambda}\right)=0
\tag{B-10}
\end{equation}
That's why $\:\dot{\mathbf{e}}_{r}=\dot{\theta}\mathbf{e}_{\theta}\:$, that is $\:\mathbf{e}_{\theta}\:$, is always normal to $\:\mathbf{e}_{r}\:$.
For the acceleration $\:\mathbf{a}\:$ we have from (B-06)
\begin{equation}
\mathbf{a}=\dot{\mathbf{v}}=\dfrac{d\mathbf{v}}{dt}=\dfrac{d\left(r\dot{\theta}\mathbf{e}_{\theta}\right)}{dt}=\left(-r\dot{\theta}^2\right)\mathbf{e}_{r}+\left(r\ddot{\theta}\right)\mathbf{e}_{\theta}
\tag{B-11}
\end{equation}
since from (B-07)
\begin{equation}
\dot{\mathbf{e}}_{\theta}=\;-\;\dot{\theta}\mathbf{e}_{r}
\tag{B-12}
\end{equation}
Equation (B-11) is written as
\begin{equation}
\mathbf{a}=\underbrace{\left(-r\dot{\theta}^2\right)\mathbf{e}_{r}}_{centripetal}+\underbrace{\left(r\ddot{\theta}\right)\mathbf{e}_{\theta}}_{orbital}
=\mathbf{a}_{r}+\mathbf{a}_{\theta}
\tag{B-13}
\end{equation}
Acceleration vector $\:\mathbf{a}\:$ is analysed in two normal components
(1) The so called centripetal acceleration
\begin{equation}
\mathbf{a}_{r} \equiv \left(-r\dot{\theta}^2\right)\mathbf{e}_{r}
\tag{B-14}
\end{equation}
which is pointing always inwards to the center and is "trying" to change only the direction of the velocity vector $\:\mathbf{v}\:$, and
(2) The orbital (tangent) acceleration
\begin{equation}
\mathbf{a}_{\theta} \equiv \left(r\ddot{\theta}\right)\mathbf{e}_{\theta}
\tag{B-14}
\end{equation}
which is always tangent to the circle and is "trying" to change only the magnitude of the velocity vector $\:\mathbf{v}\:$.
Note that the acceleration vector $\:\mathbf{a}\:$ doesn't point to the center in general.