If I understand your problem right, you want to see why the terms are radial/tangential:
Radial
$-r \dot{\theta}^2$
is indeed the term you know from a uniform circular motion. As in that case (UCM) only the direction of the velocity changes, the acceleration is perpendicular to the velocity, thus in the radial direction.
$\ddot{r}$
if the radius is changing and the rate of this change is changing as well, this is it, so it's just the change in radial velocity. It's quite logical that this part of the acceleration is in the radial direction.
Tangential
$r\ddot{\theta}$ a change in angular velocity while keeping the radius constant. As in this case (constant radius) the movement is circular, a change in angular velocity resuls in a change of the magnitude of the velocity, so the acceleration must be tangential.
$2\dot{r}\dot{\theta}$ consider something in a uniform circular motion ($\dot{\theta}$, but no $\dot{r}$). If suddenly, the radius is changed, the magnitude of the velocity is changed ($v=r\dot{\theta}$, if $r$ changes, $v$ changes), so there must be a tangential component to the acceleration.