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Given a powder of solid substance what will happen if we make the granules smaller and smaller mechanically? Will this eventually make a liquid or gas from the powder?

Can there be gaseous substanse made not from single molecules but from microscopic granules of a solid?

Also, I wonder whether making a power finer will decrease its angle of repose to zero.

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    $\begingroup$ it depends in the substance. if the substance is ionic, it would have to decompose to become a gas as you cannot have an ionic compound gas. covalent compounds however, technically if you could grind it into individual molecules, the molecules will be able to absorb enough heat energy from the surroundings to be able to become a fluid. this is very hard to do and so we usually just heat it. $\endgroup$ – ziggy May 10 '15 at 12:19
  • $\begingroup$ @adziggy at what stage angle of repose disappears? Is it real to grind the powder so fine that it loses angle of repose? $\endgroup$ – Anixx May 10 '15 at 12:25
  • $\begingroup$ see your Qu on the chem SE, i have answered this there $\endgroup$ – ziggy May 10 '15 at 12:33
  • $\begingroup$ take into account the melting point of the substance, its a powder if its temp is below the melting point and a fluid if it is above. $\endgroup$ – ziggy May 10 '15 at 12:33
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    $\begingroup$ Unless you grind to the molecular level, it's a powder. And as others have written, given pressure and temperature inside the solid-phase region, the molecules will re-bind rather quickly, so it won't remain a fluid anyway. $\endgroup$ – Carl Witthoft May 10 '15 at 15:54
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As a close approximation of finely ground powder we can consider fullerene $C_{60}$ molecule which has a size of about $1\,nm$. There are no chemical bonds between molecules but van der Waals force holds them together and fullerene powder looks like any other fine powder: Fullerene powder source

The vapor pressure of fullerene at room temperature is practically zero. At higher temperatures it starts to sublimate and at $800\,K$ its vapor pressure reaches $10^{-5}\,bar$.

Edit: I have to clarify my argument. When fullerene is produced in plasma it exists as separate molecules. But when collected in bulk amounts, these molecules stick to each other resulting in a regular-looking powder. My point is - no matter how fine a material is milled, the result would still be an ordinary powder because small grains stick together.

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  • $\begingroup$ Fullerene is a crystallic solid: chemistry.about.com/od/periodictableelements/ig/… How do u know that the grains consist of single molecules? $\endgroup$ – Anixx May 28 '15 at 9:28
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    $\begingroup$ @Anixx: They don't consist of single molecules, that's the point. The fullerene molecules are held together by the van der Waals force and this force will bind together small granules of any other powder. That is why you should not expect granules to move independently like they are a liquid. $\endgroup$ – gigacyan May 28 '15 at 11:07
  • $\begingroup$ Why is this answer downvoted? It illustrates pretty clearly, why grinding something to a molecular level is a futile attempt, thus answering the question (answer: the question simply does not make sense conceptually). $\endgroup$ – Sebastian Riese May 28 '15 at 16:14
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What makes something a powder is that each granule has a small enough contact surface with other granules that the forces that hold the bulk material together are not strong enough to make the collection of granules rigid. This critical contact surface area will be relative to the size of the granule. When the granules get to be the size of molecules, their contact areas will no longer be small relative to the granule size, and they will clump.

If what you described were possible, then you could mechanically turn ice into water at subzero ambient temperatures, or generate room temperature liquid iron. For something to be a liquid, the molecules have to have enough kinetic energy to keep from sticking rigidly together.

As for a gas, the same thing applies. The molecules have to have even more kinetic energy to detach themselves completely. If you tried to have a gas made up of small clumps of molecules, you would be in an unstable situation. If it's hot enough so they don't clump into bigger and bigger clumps and eventually solidify, then they will smash each other into molecules. Teeny clumps have the most surface area compared to their total volume, so on a percentage basis they lose volume the most quickly. Once you get down to individual molecules, they don't smash each other apart unless it's much hotter because covalent bonds are so much stronger.

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    $\begingroup$ what is the smallest powder one can make from ice or iron? $\endgroup$ – Anixx May 29 '15 at 19:15
  • $\begingroup$ Is there some substance that cannot be reliably classified neither to liquid nor powder? $\endgroup$ – Anixx May 29 '15 at 19:16
  • $\begingroup$ I don't know the answer to the first question. I think the answer to the second question is probably No. $\endgroup$ – Mark Foskey May 30 '15 at 1:09
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The reason why steady packings of powders exist is precisely because

  • powders are athermal systems in the sense that their motion is not driven by thermal fluctuations (the particles are too big and too heavy to be bothered by thermal fluctuations)

  • powder grains have dissipative dynamics and can settle down into a mechanically equilibrated structure if one does regularly bring energy into the system (because they are big and heavy, their kinetic energy is sufficient to alter the cohesion of other particles during a collision...leading to elastic deformations dissipated in heat or plastic deformations of the particles or both)

For usual granular matter, the static properties such as achievable packing fractions and angle of repose are very much dependent on the protocol, the grain properties, its friction coefficient, its shape, the polydispersity etc...

It depends so much on the protocol and details of the experiment that it has been reported that it also depends on temperature variations. In fact since we have to deal with macroscopic grains, they can expand or contract because of temperature changes. In most packings with little friction, this can generate a loss of angle of repose momentarily until a new mechanical equilibrium is found.

Finally, I have to specify that in the case of the settlement of a powder on a substrate in absence of containing walls (context in which we can talk about angle of repose), if there is not enough friction between the grains and the substrate (if its surface is very very smooth or lubricated somehow), then the concept of angle of repose disappears and the powder literally "wets" the substrate as Aulo reported. Of course, contrary to the usual wetting of a molecular fluid, the cause here is more gravity than the van der Waals interaction between the grains and the substrate (although the latter does play some role too).

Now, for the simplest dynamical aspects, if one vibrates a powder very fast, it is possible to obtain a granular fluid regime that looks like a liquid or gas depending on the density. Despite all the efforts of the community on this topic it seems that for the specific reasons aforementioned it is impossible to get a one to one mapping between an actual fluid and a granular fluid although it is possible to rewrite most properties in a similar language. During avalanches, parts of the grains literally flow down a slope like a liquid but the velocity distribution is not Maxwellian for instance. Sand timers work on the same principle as water clocks (flowing down through a hole) but are more convenient than the latter because the flux of grains through the hole is independent of the height of the packing $h$ (contrary to most molecular fluids with a dependence on the $\sim \sqrt{h}$).

Finally, as it has been pointed out, granular flows can jam which is not the case for any molecular fluid that I know of (although this is a very controversial topic, the jamming transition has been shown to be quite distinct from the glass transition).

Now, your question is originally about downsizing the grains. That is possible up to few hundred microns at most. Below that scale, we reach the micron scale, and particles of that size are usually called colloids which refers to those particles that are neither molecules nor grains but in between. For that reason, they behave as real life toy model "molecules" once they are put in a solvent. This size dependent thermal regimes are discussed at the beginning of this paper although I have failed to retrieve the specific paper I have in mind on the subject.

In air, I am not really sure about how they behave, but most likely if you sweep some air, they will gain some altitude, attract one another via dispersion forces and can aggregate by doing so over long periods of time (that's how dust forms).

The two properties I have told about at the beginning (characteristic of powders) do not really hold anymore and the science of colloids consists then in trying to figure out how to pattern and treat these micron or sub-micron particles to make them interact in a way we like.

These colloidal systems have very rich phase behaviour including of course liquid-gas transition and fluid-solid transition among many other.

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  • $\begingroup$ Can one mechanically get such fine powder that it becomes a thermal system? For instance, loses angle of repose? $\endgroup$ – Anixx May 29 '15 at 21:42
  • $\begingroup$ I have read papers where people were looking at "powders" with grains so small that it wasn't possible to neglect thermal effect anymore to determine the packing fraction obtained by vertical tapping. So I would suppose that the angle of repose disappears then yes. $\endgroup$ – gatsu May 29 '15 at 22:11
  • $\begingroup$ are there any examples? $\endgroup$ – Anixx May 29 '15 at 23:10
  • $\begingroup$ I have added some extra details and references to my answer. I haven't been able to retrieve the paper I was talking though... $\endgroup$ – gatsu May 30 '15 at 9:45
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A powder is a state with microscopic grains, a fluid has sub-nanoscopic grains. A powder is a granular material, it therefore presents a jamming transition, where the size of grains induces non-linear flowing of the material.

This jamming transition can be seen as an effect of the rather small number of particles in such experiments. When considering a similar number of sand grains to the number of water molecules in a glass of water (about $N_{part}\simeq10^{23}$ molecules in a volume of $1cm^3$), the volume of sand would be roughly $1/1000$th of the Sahara.

When looking to the fraction of the desert you can take before seeing the ripples of dunes it would be $10^{-6}S_{Sahara}<f$. And this would lead to a minimum number of particles of $10^{17}<N_{part}^{min}$.

In the same volume of $1cm^3$ for all those grains, the maximum grain size before some waves are seen is $$ L^{max}_{grain} = \left(\frac{1cm^3}{N_{part}^{min}}\right)^{1/3} \\ L^{max}_{grain} <2.10^{-6}cm \\ L^{max}_{grain} <20 nm $$

This size is 4 order of magnitude below the size of a sand grain. This would indeed require quite a lot of energy (like reducing a mountain like the Everest into blocks of 1 meter in size)...

Finally regarding the existence of a gas of such fine particles, I would refer to the monitoring by NASA of sand going from the Sahara to the Amazon. The distinction between a gas and a liquid there is only a matter of density.

EDIT : Hasty conclusion about the angle of repose.

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  • $\begingroup$ " And yes, given a large enough number of particles or small enough sizes, the angle of repose tends to zero." - source? $\endgroup$ – Anixx May 29 '15 at 17:13
  • $\begingroup$ "theoretically you could make a liquid out of grains, but the energy required to grind them will be gigantic." - source and examples $\endgroup$ – Anixx May 29 '15 at 17:13
  • $\begingroup$ "As far as anyone can tell there is no mountain to climb in order to enter this desert, so we could say that its angle of repose is roughly zero." - no, you cannot say so, sand has fixed angle of repose, far from zero. Non-existence of a high mountain is due to wind and initial conditions, but you do not need a high mountain to measure the angle of repose. You need just a handsome of sand (for a high mountain in absence of wind the angle of repose would be essentially the same). $\endgroup$ – Anixx May 29 '15 at 17:14
  • $\begingroup$ Sand has fixed angles of repose, and so has water on the border of a container, the meniscus. Then everything has an angle of repose. $\endgroup$ – Aulo May 29 '15 at 17:18
  • $\begingroup$ totally wrong. Meniscus is caused by surface tension. In a body of water far from the ages in contact with other materials a drop will disappear without a trace. Water has ZERO angle of repose. $\endgroup$ – Anixx May 29 '15 at 17:21
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Why is solid not big gas particles. Where is the boundary between metals and non metals. Their properties? Their form? When does one change into the other. When does something stop and start being an antenna?

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