I'm looking at two-electron Helium atoms where one electron is in the ground state (due to if it were in other states, it's de-excitation would simply lead to the ionization of the electron). The other electron is in an arbitrary excited state.
What does this notation mean in terms of the allowed wavefunctions?:
Specifically, for the singlet state, I understand that the both electrons must have opposite spin to give a total overall spin of Zero (correct me if I'm wrong). But why does this mean suddenly the wavefunction, $\psi_{+}$ is allowed to be symmetric. I thought all fermion wavefunctions had to be anti-symmetric havinga $\psi_{-}$ state.
For the triplet state, as I understand it, the electrons have a total spin number of 1 meaning that they have to have the same spin as each other (+1/2 each or -1/2 each). Is this correct? Further to this, I don't specifically understand the notation in the equations above. Specfically, I don't understand the last bit added on the end:
What does this actually mean?
I understand this might be a silly question as it could just be me mixing up notation but any help will be appreciated. Thank You! :)
EDIT: See AV23 Comment below. Answer! :) Basically, find the $\hat{S}^{2}$ eigenvalues to deduce S using below: