How can we see that the group $N$ generated by $$ g = (e^{2\pi i/3} I, -I, e^{i\pi /3}) \in SU(3)\times SU(2)\times U(1) $$
acts trivially on all fields in the Standard Model?
First of all, note that $g$ is in the center of $SU(3)\times SU(2)\times U(1)$. Therefore its representative in the adjoint representation is the identity. Since gauge bosons transform in the adjoint representation, $N$ acts trivially on them.
The left-handed lepton fields are in the trivial representation of $SU(3)$ and are an $SU(2)\times U(1)$ doublet, $$\Psi = \begin{pmatrix} \nu_L \\ \psi_L \end{pmatrix}.$$
Baez is using a normalization of charge such that these fields have $U(1)$ charge $-3$., so they also transform trivially under $N$.
The right-handed lepton $\psi_R$ has $U(1)$ charge $-6$ in this system, so it too is trivial.
The left (right) handed quarks have $U(1)$ charge $1$ ($4$ or $-2$) in this system and transform under $SU(3)$. It is simple to see that they also transform trivially under $N$.
(Note that various sources put the $1/3$ ratio between quark and lepton charges in various places, so be careful comparing.)