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Let's assume we have an electrochemical cell, like an AA battery. We attach a long straight wire to the negative terminus of the battery, the other end of the wire extends right away from the battery along the battery's long axis.

How do free electrons distribute themselves along such a wire?

We know that the negative terminal of a battery has a surplus of free electrons. We also know from If we connect a long wire to a battery, will battery produce more electrons? that the battery will pump some extra free electrons into the wire.

Electrons mutually repulse each other. So in an isolated charged conductor they would distribute themselves evenly, if the electric field is uniform. In our case the electric field is not uniform: the positive terminal of the battery would tend to pull the free electrons toward the battery. So we have two opposing forces. Also, the electrons do not know where the negative electrode of the battery ends and the wire begins. For them the electrode with the attached wire is the same as just one big negative electrode.

We know that electrons distribute themselves so that potential difference between any point of the wire and the positive terminal of the battery would be about the same. The voltage drop along the wire occurs only because of the resistance of that part of the wire, which is rather small.

What mathematical function would describe the distribution of the free electrons?

Would the charge density be about the same along the whole wire, or it will be considerably higher near the negative terminal of the battery (because of the pull by the positive terminal)?

Thank you.

Edit №1: If the task is too complex, let's simplify it by assuming the wire has no resistance, and it is infinitely thin, to disregard the surface area / effects. I am interested in only the lengthwise distribution along the wire.

Edit №2: What I seek to understand in this case: how would free extra electrons distribute themselves along a conductor in an external electric field to create an equal potential?

Now I see that the task, as I put it originally, is indeed very complex, mostly because of the complexity of the battery's internal structure.

Let's simplify the task to the utmost.

Firstly, let's approximate the battery by such electrochemical cell:

(fig.1)enter image description here

Let's disregard the casing and the edge effects.

My view is such a cell can be approximated by a parallel plate capacitor, where there is a limited and constant amount of charges on the plates and the electrolyte can resupply the charges if they flow away from the plates. Thus, the charges in the cell would distribute themselves like they do in a charged capacitor: along the opposite surfaces of the electrodes.

(fig.2)enter image description here

Now, let's add a wire to the (-) electrode of the cell by sequentially adding infinitely small portions of an ideal conductor.

(fig.3)enter image description here

Such a system can be approximated by a charged capacitor with an attached wire. With each added portion of the wire we increase capacity of the subsystem "negative electrode + wire". Thus the subsystem can be approximated by multiple capacitances connected in series. The total capacitance will be a sum of all capacitances. Let's disregard the surface and edge effects.

Now, for each small capacitance to have the same potential it must have the same charge. Thus, the free extra electrons in the wire will distribute themselves evenly along the wire, and the external electric field of the positive electrode will be canceled out by the electrons that pile up at the opposite surface of the negative electrode, like in a regular capacitor.

Is this reasoning correct? Can you provide a more scientific explanation?

Edit №3:

Another way to explain it: The electrons that pile up in the negative electrode as shown above, cancel out the electric field, created by the positive charges. But at the same time they create their own negative electric field in the negative electrode that would tend to push electrons out of the negative electrode provided there is a path for them to escape.

Let's connect a short piece of wire (wire 1) to the negative electrode of the battery. Before we connect it, the wire has a zero potential, while the negative terminal of the battery has, say, minus 0.75 V potential. Thus we have a potential difference between the wire and the negative electrode. After we connect them, electrons form the electrode will flow into the wire (pushed by the negative electric field described above) until they cancel out the potential difference between the wire and the negative electrode of the battery. Thus the potential of the wire will reach that of the negative electrode.

The same follows if we further connect one more piece of wire (wire 2), and so on, thus every other piece of wire will be reaching the same potential as the negative electrode of the battery, as the electrons will flow into it to neutralize the potential difference.

Is this reasoning correct? Can you provide a more scientific explanation?

Edit №4:

Let's further simplify the task. Assume we have a charged parallel plate capacitor. We connect a long wire to one plate. We know that potential difference between the positive plate and the wire will be the same at any point of the wire.

(fig.4)enter image description here

How do free electrons distribute themselves along the wire to create an equal potential at any point of the wire? (disregarding the surface and edge effects)

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  • $\begingroup$ Your question is a special case of a much more general question: "How is the charge distributed over a charged object?". Have a browse through these questions for some info. $\endgroup$ – John Rennie Jan 30 '15 at 17:48
  • $\begingroup$ @John Rennie, Thank you for the suggestion, I will give it a look. If it is not too much trouble, could you just maybe hint me as to how would free electrons be distributed? Would it be about uniform distribution? $\endgroup$ – Santa Claus Jan 30 '15 at 17:55
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    $\begingroup$ It's actually a really hard problem. Generally speaking charge prefers less curved surfaces so you'd get roughly even charge over the middle bit of the wire and a lower charge density at the ends. I don't know how to make this quantitative. Googling didn't find any answers (there's lot's for infinite cylinders but not for finite ones) so I suspect it's a hard problem. $\endgroup$ – John Rennie Jan 30 '15 at 18:00
  • $\begingroup$ Thank you for the time. Well, let's solve it otherwise, use approximations. We know that potential is about the same along the wire, we know that there is a pull from the battery's positive end, and the mutual repulsion of electrons. What do your guts tell you? I think a potential in a point is created mostly by the charges in and around this point. This kind of suggests an about uniform distribution? $\endgroup$ – Santa Claus Jan 30 '15 at 18:13
  • $\begingroup$ Charge density of a wire changes linearly when the wire is in an uniform electric field. A short piece of wire can be said to be in an uniform field. How much the charge density changes per some short distance is proportional to the field strength. Don't these two facts give quite good general idea about charge distribution? $\endgroup$ – stuffu Jul 22 '15 at 20:27
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There is no effect on the electrons. It is not like a pipe connected to tap and stopped at the other end so that even before unstopping the other end the molecules are being squashed inside. No repulsion as you are thinking of. In the battery case as soon as you connect the + end the current starts to flow. Think of it as not a mechanical force that drives the electrons but the potential difference. so at least two terminals need to be there.

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  • $\begingroup$ We know that in a charged capacitor free extra electrons are concentrated on the negative plate, they are held there by the electric pull produced by the positive plate. Do you think the electric field of the battery does not pull free electrons? $\endgroup$ – Santa Claus Jan 30 '15 at 17:33
  • $\begingroup$ Actually it is just like attaching a stoppered pipe to a tap. You won't get many extra electrons onto the wire just like you won't get much extra water into the pipe. But you will get some. $\endgroup$ – John Rennie Jan 30 '15 at 17:40
  • $\begingroup$ Yes electric forces operate in a capacitor as you have said. but the cell's driving force is chemical energy. Nevertheless potential difference means that there is an electric field along the circuital loop. So when you have only -ve end connected, it is negative with respect to nothing! the circuital loop doesn't completes and no electric field to push the electrons mechanically/electrically. When you have the +ve end too, the potential difference sets up (End A is negative than end B, say) force begins to thrust electrons. $\endgroup$ – Coward Jan 30 '15 at 17:42
  • $\begingroup$ The battery is just a chemical version of a van der Graaff generator - both just pump electrons. The vdG manages to charge its metal sphere. $\endgroup$ – John Rennie Jan 30 '15 at 17:45
  • $\begingroup$ @John Rennie Ok. Let's say, the negative terminal of the battery has 1000 extra free electrons. After we attach a wire, a battery will produce some more, say, 100 more electrons. How would these 1100 extra free electrons distribute themselves along the wire? $\endgroup$ – Santa Claus Jan 30 '15 at 17:47
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The electrons do not even enter the wire, because the redox reaction between the substances in each of the nodes never occurs. Once the wire is connected to each of the nodes, electricity will flow through as electrons will be more attracted to the node with the greater reduction potential.

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