How to identify the represented group from the basis states?

There is a 6 dimensional multiplet belonging to an irreducible representation of a unitary group of rank less than 3. How does one check if the states $|i\rangle$ belong to spin 5/2 representation of $SU(2)$ or they belong to 6 dimensional representation of $SU(3)$?

For a given choice of basis states of the Hilbert space, one can, in principle, obtain a representation of any group, the dimension of the representation being the same as that of the Hilbert space. Just by knowing the basis states, I think it may not be possible to identify which group has been represented. Is my conclusion correct, or there is some point I am missing?

If I know the explicit form of the states I would first apply the SU(2) generators to them. For example apply the Cartan generator $L_3$ and see whether you get the eigenvalues $-5/2, -3/2,...,+5/2$.
• Well the explicit form of the algebra generators depend upon a chosen basis. They change their explicit matrix form under similarity transformation. So... what I told you to do will not work unless you're using the same basis for generators and states. Anyway, you definitely need some extra information do determine the algebra. If I give you only six states $|i\rangle$ and nothing else, you can't even say they belong to an irreducible representation. – Diracology Oct 29 '14 at 16:43