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This engineering toolbox table shows thermal conductivity of steam at 0.016. I understand that water is better in conducting heat than air, but if I read this correctly, steam is worse in conducting heat than water? Would there be any difference of steam in a vacuum? Or would it be also 0.016?

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    $\begingroup$ What does "steam in a vacuum" mean? If there's steam, it's not vacuum. $\endgroup$
    – ACuriousMind
    Commented Sep 18, 2014 at 21:23
  • $\begingroup$ That seems to be very temperature and pressure dependent: thermopedia.com/content/1150 $\endgroup$
    – CuriousOne
    Commented Sep 18, 2014 at 21:26
  • $\begingroup$ "steam in vacuum" means that boiling water first forced out the air of a vessel and a gasketed lid prevents air to enter the vessel again. So technically, the vessel interior is under a lower pressure, but a heat source still can create water to boil inside. I am trying to figure out the heat conductivity of this steam inside the vessel. $\endgroup$ Commented Sep 18, 2014 at 21:33
  • $\begingroup$ the vessel interior is under a lower pressure - see youtube.com/watch?v=Zz95_VvTxZM $\endgroup$
    – LDC3
    Commented Sep 19, 2014 at 13:37

2 Answers 2

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From a heat transfer perspective, steam is a lot more like air that it is like liquid water. The chemical makeup doesn't matter as much as the state.

As a gas, steam is a bunch of $H_2O$ molecules flying around at random, bashing into each other occasionally. The mechanism of conduction in that case is that the hot molecules will gradually bounce past the cold (and vice-versa), moving heat across a temperature gradient. The same is true for air, so their conductive properties are similar.

As a liquid, those molecules are much more tightly packed and are in contact (sort of) with each other all the time. When you heat up molecules in one place they can transfer that heat directly to their neighbors. At the molecular scale heat is just a lot of wiggling, spinning and vibrating motion (electrons get involved too if it's hot enough). Being in contact makes it easy for vibration in one molecule to make its way to others.

The pressure dependence in steam (an other gases) shows up at two extremes. At high pressure, the molecules will get closer together as they fly around and start to act a bit more like a liquid. At very low pressures, they'll collide so rarely that some of the molecules will go clear across the space in question without hitting any of the others. That the low pressure effect depends on both pressure and the size of the system

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  • $\begingroup$ But, at comparable gas temperatures, can the water molecule (as vapor) carry more energy than a nitrogen molecule, for example, due to the water molecule having more degrees of freedom by which it can vibrate? And would that allow the water molecule to better transfer heat? Or is the heat all tied up only in the translational kinetic energy of the molecules? $\endgroup$
    – docscience
    Commented Feb 8, 2017 at 20:59
  • $\begingroup$ So, this is funny. I looked up the conductivity of steam and $N_2$ (Incropera&DeWitt 0.0339,0.0389 rsp.). I expected water to be higher for your stated reason (also water has a smaller kinetic diameter and lower molecular weight). ¯_(ツ)_/¯ $\endgroup$ Commented Feb 25, 2017 at 16:20
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If you got vaccum inside a closed container, you would get the water inside or(some water) goes to vapor directly without any heat source till you get some equilibrium.

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