Let the entities $\psi^i$ transform as the fundamental representation of $\mathrm{SU}(n)$, denoted by ${\bf n}$: $$ \psi^{\prime i}=U^{i}_{~j}\psi^j, $$ where, of course, $U$ represents $n\times n$ unitary matrices with unit determinant. Taking complex conjugates on both sides, we get, $$ \left(\psi^{\prime i}\right)^{*}=\left(U^{i}_{~j}\right)^{*}(\psi^j)^{*}. $$ Introducing the notation $$ \psi_i=\left(\psi^i\right)^{*}, \quad U_{i}^{~j}=\left(U^{i}_{~j}\right)^{*},\tag{1} $$ we have $$ \psi^\prime_i=U_{i}^{~j}\psi_j. $$ Therefore, by definition, $\psi_i=(\psi^i)^{*}$, which transform as $\bar{\bf n}$.
On the other hand, if I am not wrong, for the group $\mathrm{SU}(2)$, $\psi_i$ is also defined to be equal to $$\psi_i=\varepsilon_{ij}\psi^j.\tag{2}$$
How can we have two different definitions [in (1) and in (2)] for the same object $\psi_i$?