The Einstein field equations give you the dynamical equations for the metric tensor, which is taken as a second rank tensor field whose evolution describes the evolution of the background. The Klein Gordon equation is the dynamical equation for a scalar field in a fixed background. They are fundamentally different things.
What you can do of course, is to start with an action that has a scalar field coupled to gravity (this could be done in many ways), and by varying the action with respect to the scalar field (or the matter field) obtain the Klein Gordon equation. Note that this is not a special case of the Einstein equations since in deriving those, we vary the Einstein Hilbert action with respect to the metric tensor field. You don't need a dynamical background (metric) to derive the Klein Gordon equation, and you don't need a scalar field to derive the Einstein equations.
Update in response to a comment:
The divergence of the energy momentum tensor being zero is true and has a more geometrical origin (called the Bianchi identity), but the equations of motion depend on the matter Lagrangian. That is to say, even for a scalar field you could have any Lagrangian. The usual Klein Gordon Lagrangian has a specific form for the EM tensor. But I could very well have a different Lagrangian with a scalar field (eg the $\phi^4$ theory). In this case, the form of the EM tensor will also be different. This EM tensor will also be divergenceless, but demanding this will not give you the KG equation.
As an aside, note that dynamical equations for a matter field (or any field) are obtained by varying the action with respect to that field. As I mentioned previously, the Einstein equations are obtained by varying the (Einstein-Hilbert) action with respect to the metric.
Further, regarding the point about the vanishing divergence of the EM tensor. It can be shown that if I have an action of the form $\mathcal{S}_Q = \int d^4 x \text{ }\sqrt{-g} Q$ where $Q$ is a scalar, then demading that $\delta \mathcal{S}_Q = 0$ will always give me some tensor $M^{\mu \nu}$ such that $\nabla_{\mu}M^{\mu \nu} = 0$. The fact that the Einstein tensor and the EM tensor obey this are simply examples of this more general fact.