Let us suppose that we have an Hamiltonian that describes a quantum system. If one would like to know all of the possible values that the energy of the system described by that hamiltonian, one has to solve
$$ \hat{H}\psi_m = E\psi_m $$
Where $ \hat{H} $ is the hamiltonian operator and $ E $ is the eigenvalue for the eigenstate $ \psi_m $. My question is, if I denote $ \Psi $ by
$$ \Psi = \sum_m c_m \psi_m $$
where the sum is on all the eigenstates, do I get the "famous" $\Psi$ that has the property that $ \lvert\Psi\rvert^2$ is the probability to find the particle(s) 0f the system in some position or the other? And do the $ \psi_m $ also have this property?