0
$\begingroup$

I am trying to solve a free 1D particle non-relativistic Schrodinger equation with initial wavefunction $\psi(x,0)=\delta(x)$, where $$\delta(x)=\lim_{a\to0}(a/2)|x|^{(a-1)}.$$

Here is my approach:

Set $$i\hbar \frac{\partial}{\partial t} \Psi (x,t) =E\Psi(x,t)= -\frac{\hbar^2}{2m} \frac{\partial^2}{\partial x^2} \Psi (x,t).$$

The general solutions look like:

$$\Psi=Ae^ae^b$$

Because the sign of real number $E$ could be arbitrarily defined, I choose $E<0$ to make the solution normalizable.

$$\Psi(x,t) = A e^{-kx+i\omega t} $$

$$\Psi^*\Psi\equiv\delta(x)$$

Am I right?

How do I get the sensible solution depicting the evolution of density function of a free particle on $\mathbb R$? (like the gif video in https://en.wikipedia.org/wiki/Uncertainty_principle)

A second approach is to consider $E>0$ and set boundary conditions like a particle in a "very large" 1-D box. Could you please help me with it?


From the top answer by Jan, I learnt three ways to deal with un-normalizable wave functions.

Normalizing the solution to free particle Schrödinger equation

One of them was "use only normalizable functions to calculate probability"


The solution process was learnt from http://hyperphysics.phy-astr.gsu.edu/hbase/quantum/Scheq.html#c2


Sorry if the question is already asked.

$\endgroup$
1

1 Answer 1

2
$\begingroup$

... seems to me there are several problems here.

  1. $\psi(x)=\delta(x)$ is not an eigenfunction of the Hamiltonian, so searching for a solution to the time-independent Schrodinger equation is not useful. The solution with your initial condition will be a superpositoin of plane waves since plane waves are eigenfunctions of the free-particle problem.
  2. If $\Psi(x,t)=Ae^{-i(\omega t-kx)}$, the $\Psi(x,t)^*\Psi(x,t)=\vert A\vert^2$, not $\delta(x)$. Moreover, your $\Psi(x,t)$ is a plane wave and so certainly not concentrated at a point for any value of $x$.
  3. Next, if you are solving for a free particle, then $E$ should be non-negative since the kinetic energy is non-negative.

Since the free-particle solutions are of the form $e^{ikx}$ at $t=0$, why not try $$ \psi(x)=\int_{-\infty}^{\infty}dk\phi(k) e^{ikx} $$ i.e. find $\psi(x)$ as a wave packet and look for a function $\phi(k)$ such that $\psi(x)=\delta(x)$? You might want to recall that \begin{align} \delta(x-x_0)=\langle x\vert x_0\rangle &= \int_{-\infty}^{\infty} dk \langle x\vert k\rangle\langle k\vert x_0\rangle\, ,\\ &=\int_{-\infty}^\infty dk \frac{1}{2\pi}e^{ik(x-x_0)}\, . \end{align}

$\endgroup$

Your Answer

By clicking “Post Your Answer”, you agree to our terms of service and acknowledge you have read our privacy policy.

Not the answer you're looking for? Browse other questions tagged or ask your own question.