For a single qubit Hadamard gate, the representing matrix is $$\frac{1}{\sqrt{2}}\begin{bmatrix}1&1\\1&-1\end{bmatrix}$$ And if you apply this to the state $|0\rangle$ you get $$\frac{|0\rangle+|1\rangle}{\sqrt{2}} \, .$$ This state can be rewritten as $$ \frac{\begin{bmatrix}0\\1\end{bmatrix}+\begin{bmatrix}1\\0\end{bmatrix}}{\sqrt{2}} \quad \text{or} \quad \frac{\begin{bmatrix}1\\1\end{bmatrix}}{\sqrt{2}} \quad \text{or} \quad \frac{1}{\sqrt{2}} \begin{bmatrix}1\\1\end{bmatrix} \quad \text{or} \quad \begin{bmatrix}\frac{1}{\sqrt2}\\\frac{1}{\sqrt2}\end{bmatrix} $$ right?
If so, using this, let's say you have the superposition $\alpha |0\rangle + \beta |1\rangle$. Can you then plug it in and get $\begin{bmatrix}\frac{\beta}{\sqrt2}\\\frac{\alpha}{\sqrt2}\end{bmatrix}$? So if you started with a qubit represented by the vector $\begin{bmatrix}0.5\\0.75\end{bmatrix} \, ,$ say, then you'd end up with $\begin{bmatrix}\frac{0.5}{\sqrt2}\\\frac{0.75}{\sqrt2}\end{bmatrix} \, ,$ right?
Edit: So, overall, I'd say I'm having trouble figuring out exactly why you'd write it as $\frac{|0\rangle+|1\rangle}{\sqrt{2}}$ when you could write it as $\begin{bmatrix}\frac{\beta}{\sqrt2}\\\frac{\alpha}{\sqrt2}\end{bmatrix}$, which strikes me as easier to do calculations with (though again, that's just me).