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The CKM matrix is known to be unitary.

Now, is it just found experimentally?

Is the following idea correct?

We know that the weak force eigenstate $ \left( \begin{array}{c} d' \\ s' \\ b' \end{array} \right) $ are related to the physical state $ \left( \begin{array}{c} d \\ s \\ b \end{array} \right) $ via the Cabibbo-Kobayashi-Maskawa (CKM) matrix : $$ \left( \begin{array}{c} d' \\ s' \\ b' \end{array} \right) = V_{CKM}\left( \begin{array}{c} d \\ s \\ b \end{array} \right)$$

Orthogonality of the weak force eigenstates AND of the physical states dictates that: $$ ( d' s' b' ) \left( \begin{array}{c} d' \\ s' \\ b' \end{array} \right) = ( d s b ) \left( \begin{array}{c} d \\ s \\ b \end{array} \right) = 1 $$

SO:

$$1 = ( d' s' b' ) \left( \begin{array}{c} d' \\ s' \\ b' \end{array} \right) = V_{CKM}^{\dagger} V_{CMK} ( d s b ) \left( \begin{array}{c} d \\ s \\ b \end{array} \right) = V_{CKM}^{\dagger} V_{CMK}$$

Therefore $V_{CKM}^{\dagger} V_{CMK} = 1$

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Your last equation does not make sense. On the left had side you have a scalar 1, while on the right hand side there is supposed to be the unit matrix. However, it is $$ 1=\begin{pmatrix}d' & s' & b'\end{pmatrix}\begin{pmatrix}d' \\ s' \\ b'\end{pmatrix} = \begin{pmatrix}d & s & b\end{pmatrix}V_{CKM}^\dagger V_{CKM}\begin{pmatrix}d \\ s \\ b\end{pmatrix}. $$ Now, since the $\begin{pmatrix}d \\ s \\ b\end{pmatrix}$ form an orthonormal basis, $V_{CKM}^\dagger V_{CKM}$ has to be the unit matrix. In general, if for an orthonormal basis $\{v_i\}$ of a vector space $V$, there is a Matrix $M$ such that $$v_i^\dagger M v_i =1$$ for all $i$, then $M$ must be the unit matrix.

In general, a change of bases between two orthonormal bases is always unitary.

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