Spontaneous electroweak symmetry breaking (i.e. $SU(2)\times U(1)\to U(1)_{em}$ ) is at scale about 100 Gev. So, for Higgs mechanism, gauge bosons $Z$ & $W$ have masses about 100 GeV. But before this spontaneous symmetry breaking ( i.e. Energy > 100 GeV) the symmetry $SU(2)\times U(1)$ is not broken, and therefore gauge bosons are massless.
The same thing happens when we go around energy about $10^{16}$ GeV, where we have the Grand Unification between electroweak and strong interactions, in some bigger group ($SU(5)$, $SO(10)$ or others). So theoretically we should find gauge bosons $X$ and $Y$ with masses about $10^{16}$ GeV after GUT symmetry breaks into the Standard Model gauge group $SU(3)\times SU(2)\times U(1)$, and we should find massless X and Y bosons at bigger energies (where GUT isn't broken).
So this is what happened in the early universe: when temperature decreased, spontaneous symmetry breaking happened and firstly $X$ & $Y$ gauge bosons obtained mass and finally $Z$ & $W$ bosons obtained mass.
Now, I ask: have I understood this correctly? In other words, if we make experiments at energy above the electroweak scale (100 GeV) we are where $SU(2)\times U(1)$ isn't broken and then we should (experimentally) find $SU(2)$ and $U(1)$ massless gauge bosons, i.e. $W^1$, $W^2$, $W^3$ and $B$ with zero mass? But this is strange, because if I remember well in LHC we have just make experiments at energy about 1 TeV, but we haven't discovered any massless gauge bosons.