I am assuming you have 2 particles facing each other, and that they are approaching each other ?
First, as mentioned elsewhere on this page, "..a particle moving at the speed of light does not experience time, and thus is unable to make any measurements."
Instead, let's change the particle #1 that you are sitting on to having a specific velocity that is less than c, and particle #2 will remain as v=c.
If your v=0, the combined velocity between you and particle #2 = c, and if you measure its velocity, you will measure a velocity of c.
If you accelerate to a new velocity, and v=100,000 km/s, the combined velocity between you and particle #2 will be 100,000 km/s + 300,000 km/s = 400,000 km/s, but you will still measure the velocity of particle #2 as c.
If you accelerate to a new velocity, and v=260,000 km/s, the combined velocity between you and particle #2 will be 260,000 km/s + 300,000 km/s = 560,000 km/s, but you will still measure the velocity of particle #2 as c.
In other words, you can change your velocity to a vast range of different velocities, yet when it comes to "measuring" the velocity of particle #2, the result is always c. This can be verified if you use the velocity addition equation. The important point is that neither particle has exceeded the speed of light. The combined velocity between 2 moving particles is a different matter altogether.