Edit: Justification tofor the choice of expansion in weird time derivative.
I think I understand your struggle from your comment. I struggled a lot with this thing, too, because no author (except Chapman itselfhimself) bothers to explain where does this weird derivative comes from.
The punchline is that, you don't need it. Tong does not use it, Kardar does not use it... Hell, even Landau and Lifshitz do not use it. If you read Kirkpatrick, he uses it,it; if you read literature on granular systems, they use it. Mostly, academic articles use it because it is convenient, but pedagogical texts don't. They don't use it because this weird derivative is very useful (as a formal tool) but washes ofoff the details of the pertubationperturbation. On top of that, you never go, practically beyond the first order because the second and third order give you the so called-called Burnett and super-Burnett equations that are unstable (no stable homogeneous state). They include the third and fourth derivativederivatives in the space of the hydrodynamical field.
The spatial and temporal dependence of the microscopic distribution function can be fully incorporated in the macroscopic fields $f(r, v, t) \equiv f(\rho(r, t), T(r, t), u(r, t)|v)$. The dependence on the macroscopic term is "functional", meaning that you can have a term proportional to $\nabla T$, for example.
$f$ can be pertubativelyperturbatively expanded in gradients of the field: $$f(\rho(r, t), T(r, t), u(r, t)|v)=f^{(0)}+\epsilon f^{(1)} + \epsilon^2 f^{(2)}+\ldots $$ $f^{(0)}$ depends only directly on the fields and is assumed to be the local equilibrium approximation of $f$. $f^{(1)}$ contains term like $\nabla \rho$, $f^{(2)}$ terms like $\nabla\cdot(\nabla T)$. $\epsilon$ isis a formal parameter. The validity of the method stands on the smallness of the higher order terms, hence on the smallness onof the gradients, and hence on a small Knudsen number. That's why usually we usually say that $\epsilon$ is related to the Knudsen number (and indeed, you can do an expansion in the Knudsen number). But here, $\epsilon$ is just a term that orders the series in number of gradients.
$\int f^{0} dv=\int f dv = \rho$$\int f^{0} \mathrm{d}v=\int f \mathrm{d}v = \rho$, $\int f^{0} v dv=\int f v dv = \rho u$$\, \int f^{0} v \mathrm{d}v=\int f v \mathrm{d}v = \rho u$ and $\int f^{0} 0.5mv^2 dv=\int f 0.5mv^2 dv = 0.5\rho T$$\int f^{0} \, 0.5 \, mv^2 \mathrm{d}v=\int f 0.5 \, mv^2 \mathrm{d}v = 0.5\rho T$. WhichThis means that the hydrodynamical field areis given by the integral of the local equilibrium term.
And that's all. A useful thing onone can do (I don't really have a source on that, but I find it really nice) is to rescale the gradient as followfollows: $\nabla \to \epsilon \nabla$.
Now, let's quickly go over the method, the. The Boltzmann equation reads:
$$\partial_t f + \epsilon v\partial_x f = J(f, f)$$$$\partial_t f + \epsilon v\partial_x f = J(f, f).$$
If you inject the pertubationperturbation series, you are mostly done (after pages of computation):
The zeroth-order order is given by terms without any $\epsilon$. Which you might think is given by:
Please stop reading here, and ask yourself if you are really not including any higher order term in $\epsilon$ here?. We know that $f^{(n)}$ is of order $\mathcal{O}(\epsilon^0)$ $\forall n$ . But, is $\partial_t f^{(n)}$ of order $\mathcal{O}(\epsilon^0)$? Said differently, can the derivative create terms proportional to $\epsilon^m$?
Of course, I'm asking, so you are indeed including higher order term, let's-order terms. Let's see how. We recall that $f$ has time dependence through the hydrodynamical fields:
$$\partial_t f^{(0)} = (\partial_t \rho) \partial_\rho f^{(0)}+(\partial_t u) \partial_u f^{(0)}+(\partial_t T) \partial_T f^{(0)}$$$$\partial_t f^{(0)} = (\partial_t \rho) \partial_\rho f^{(0)}+(\partial_t u) \partial_u f^{(0)}+(\partial_t T) \partial_T f^{(0)}.$$
But, the time derivative of a field is just ana hydrodynamical equation, take. Take $\rho$ for example:
$$\partial_t\rho = -\epsilon\partial_x (\rho u)$$$$\partial_t\rho = -\epsilon\partial_x (\rho u).$$
thisThis equation, will itself have different gradients, and somehow, if you want your perturbation to be consistent, you also have to correctly keep track of the order of this derivative. Which can, therefore, be expressed as an expansion in termterms of gradients:
Where in the second line, we defined the symbol $\partial_t^{(i)}$ which, which you will agree is not a derivative but just the term of a "series" expansion. With this insight, we can go back to our expansion of the derivative of the microscopic velocity distribution:
\begin{split} \partial_t f^{(0)} &= (\partial_t^{(0)} \rho + \epsilon (\partial_t^{(1)} \rho) + \dots) \partial_\rho f^{(0)}\\ &+(\partial_t^{(0)} u + \epsilon (\partial_t^{(1)} u) + \dots) \partial_u f^{(0)}\\ &+(\partial_t^{(0)} T + \epsilon (\partial_t^{(1)} T) + \dots) \partial_T f^{(0)} \end{split}\begin{split} \partial_t f^{(0)} &= (\partial_t^{(0)} \rho + \epsilon (\partial_t^{(1)} \rho) + \dots) \partial_\rho f^{(0)}\\ &+(\partial_t^{(0)} u + \epsilon (\partial_t^{(1)} u) + \dots) \partial_u f^{(0)}\\ &+(\partial_t^{(0)} T + \epsilon (\partial_t^{(1)} T) + \dots) \partial_T f^{(0)}. \end{split}
More simply, we see that $\partial_t^{(i)}$ is not a "real time"-time" derivative, but still follows a kind of chain rule (and other properties of the regular derivative) such that we can rewrite the above expression as:
Which is what we wanted to see. Note then that the correct zero order-order Boltzmann equation is not:
$$ \partial_t f^{(0)} = J(f^{(0)}, f^{(0)})$$$$ \partial_t f^{(0)} = J(f^{(0)}, f^{(0)}),$$
$$ \partial_t^{(0)} f^{(0)} = J(f^{(0)}, f^{(0)})$$$$ \partial_t^{(0)} f^{(0)} = J(f^{(0)}, f^{(0)}).$$
We can perfectly work with only $\partial_t$. When we do so, we have to be careful because even if $f$ does not contain terms proportional to $ \epsilon$, $\partial_t f$ dodoes contain terms proportional to $\epsilon$. Hence, we must expand the derivative as a serieseries in power of $\epsilon$ to consistently, order by order, arrange all terms in $\epsilon$\epsilon$.
The method above is equivalent to writing $\partial_t g = (\partial_t g)_0 + \epsilon ^1(\partial_{t} g)_1 + \dots$. But a nice thing is that $(\partial_{t} g)_m$ behavebehaves as a derivativederivative. Hence, it suggests us towe write it down in the form: $\partial_t g = \partial_t^{(0)} g + \epsilon\partial_t^{(1)}g + \dots$. Using the chain rule, it will create terms like $(\partial_t^{(1)}T)\partial_T g$, where $\partial_t^{(1)}T$ has to be understood as the contribution of order $\epsilon$ in the time derivative of $T$ (or equivalently linear inin the gradients, note the discrepancy between what I say here and what is said in your article. In your article, $\epsilon^0$ corresponds to a linear gradient,gradient; in my case, $\epsilon^0$ corresponds to zero gradient. This is because I rescaled the gradient by $\epsilon$ for simplicity.)