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Mar 27 at 9:38 vote accept Raffaella
Mar 27 at 9:36 comment added Confuse-ray30 @Raffaella The math behind this is regarding the space of parameters as a manifold, the thermodynamical potential as a scalar field and the derivatives (locally) are just the canonical basis vectors of your tangent space. Every other derivative can be obtained (clearly, because it is a basis of the vector space) as linear combinations of these (in this case 3) basis vectors.
Mar 27 at 9:33 comment added Confuse-ray30 @Raffaella Define whatever is here as a new function, say $g$ and $h$ and repeat procedure.
Mar 27 at 9:33 comment added Raffaella And why we need exactly three second derivatives to express other derivative? Is there any math behind it? Anyway, thank you for your answer!!
Mar 27 at 9:27 comment added Raffaella What if second derivative? Would it be the same?
Mar 27 at 9:18 history edited Confuse-ray30 CC BY-SA 4.0
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Mar 27 at 8:47 comment added Raffaella That's exactly what I want to ask: why can any other derivative along some direction in parameter space be expressed as a linear combination of these
Mar 27 at 8:19 history answered Confuse-ray30 CC BY-SA 4.0