A real linear operator is one whose matrix elements are real. For example, given an orthonormal basis $\{|\psi_i\rangle\}$$\{|\psi_k\rangle\}$,and an operator $\hat O$, suitably defined on a Hilbert space;space $\mathcal H$; when we calculate the expectation value of the operator: $\langle \psi_i|\hat O|\psi_j\rangle$$\langle \psi_i|\hat O|\psi_j\rangle, \;\forall |\psi_i\rangle,|\psi_j\rangle\in \{|\psi_k\rangle\}$; we always get real numbers. Because we have assumed a particular basis, the realty of an operator is not guaranteed to be a property that holds for any arbitrary basis used to span the Hilbert space. Every Hermitian operator is also a real operator, however, not all real operators are Hermitian. Although the realty of an operator is a basis dependent concept, Hermiticity is intrinsic to the operator and thus holds in any basis, i.e. $\langle\hat O\psi |\psi\rangle=\langle\psi |\hat O\psi\rangle, \;\forall |\psi\rangle\in \mathcal H$. So Hermiticity is the crucial requirement needed to do quantum mechanics, it does no good for an operator to be real in this sense, without having Hermiticity.