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Chet Miller
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The BWRS approach is based on molar volume = 1/rho. As such, to apply the Starling entropy departure equation, you start with $C_v^{IG}\ln{(T2/T1)}$ and apply the Starling entropy departure corrections to this.

Alternately, you can start with the full ideal gas relationship $C_v^{IG}\ln{(T_2/T_1)}-R\ln{(\rho_2/\rho_1)}$ and then apply the Starling entropy departure equation, with the first term omitted because it represents the ideal gas contribution of molar volume.

The BWRS approach is based on molar volume = 1/rho. As such, to apply the Starling entropy departure equation, you start with $C_v^{IG}\ln{(T2/T1)}$ and apply the Starling entropy departure corrections to this.

The BWRS approach is based on molar volume = 1/rho. As such, to apply the Starling entropy departure equation, you start with $C_v^{IG}\ln{(T2/T1)}$ and apply the Starling entropy departure corrections to this.

Alternately, you can start with the full ideal gas relationship $C_v^{IG}\ln{(T_2/T_1)}-R\ln{(\rho_2/\rho_1)}$ and then apply the Starling entropy departure equation, with the first term omitted because it represents the ideal gas contribution of molar volume.

Source Link
Chet Miller
  • 34.5k
  • 3
  • 21
  • 48

The BWRS approach is based on molar volume = 1/rho. As such, to apply the Starling entropy departure equation, you start with $C_v^{IG}\ln{(T2/T1)}$ and apply the Starling entropy departure corrections to this.