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Nov 22, 2022 at 11:39 comment added sh4dow The neon atoms will give off some thermal radiation, but in a gas the interactions between atoms are comparatively rare and the amount of emitted radiation is therefore very low (the volume absorption (or emission) coefficient is very small).
Nov 20, 2022 at 23:08 comment added James @sh4dow Thank you. In the case of of a tube of neon gas, besides emitting specific wavelength signatures due to electrons jumping from higher to lower orbitals, why don't the collection of neon atoms as a whole, which must be vibrating at current temperature, also give off Kirchoff's thermal motion radiation, thus contaminating the pure atomic spectra lines for neon?
Nov 20, 2022 at 18:46 comment added sh4dow And perhaps I should add that structures with optically interacting materials can have a thermal based emission unlike the Planck spectrum: Eg. an infrared reflecting layer would reduce the emissivity of the "system" in the infrared spectrum and leave the non-infrared emissivity untouched. And if you just describe the apparent properties of complex materials, you often get nonuniform emissivities. But you can view these systems as emitting a planck spectrum that is then modified by the optical properties of the system.
Nov 20, 2022 at 18:18 comment added sh4dow @Jasen I circumvent the complexities of absorption/emission spectra by clearly separating thermal and non-thermal components of light emission. The thermal component is universal (in form, not in magnitude), the non-thermal one is usually highly specific.
Nov 20, 2022 at 18:14 comment added sh4dow @James that kind of light emission comes from electrons being pushed to a higher energy orbital and spontaneously jumping back down while emitting the energy difference as a photon. This is why there are specific signatures - since electron orbitals have specific energy values, emitted photons always have the energy of a specific difference of two orbitals. Kirchhoff's law applies to thermal spectra, which come from the thermal motion of atoms.
Nov 20, 2022 at 10:15 comment added Jasen no this is wrong. black bodies follow the black body profile, coloured bodies basically emit the colours they don't reflect. - as in "the sympathizer"'s answer
Nov 19, 2022 at 13:12 comment added James Thank you. Does the glow that a neon gas tube, or sodium gas tube, or hydrogen gas tube emit when passed with electricity constitute "thermal radiation", or something else? Why is there a specific signature for each atom's spectrogram, would it not contradict Kirchoff's law that spectra depends entirely from temperature?
S Nov 19, 2022 at 12:50 review First answers
Nov 19, 2022 at 13:42
S Nov 19, 2022 at 12:50 history answered sh4dow CC BY-SA 4.0