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Oct 12, 2022 at 10:46 comment added Bob D Forgive my ignorance, but what do you mean by the temperature of the whole system? Do you mean equilibrium temperature? Average non equilibrium temperature? And where is the "thermostat" located?
Oct 12, 2022 at 10:38 comment added GiorgioP-DoomsdayClockIsAt-90 @BobD No, I mean that the temperature of the whole system differs from the thermostat temperature.
Oct 12, 2022 at 9:54 comment added Bob D By macroscopic do you mean finite for an irreversible process?
Oct 11, 2022 at 12:38 comment added GiorgioP-DoomsdayClockIsAt-90 @BobD Then, you should be able to derive in some way from the theory that during an isothermal change of volume, there is a macroscopic difference in temperature between the system and reservoir.
Oct 11, 2022 at 10:44 comment added Bob D @Chet Miller Your thoughts?
Oct 11, 2022 at 10:39 comment added Bob D Frankly, I don’t see how 1-4 eliminates the requirement for a temperature difference in order for energy transfer in the form of heat, if that’s what you are saying. To me it is simply another way of demonstrating rhe equivalency of the outcome of heat and work demonstrated by Joule with stirrer instead of compression work
Oct 11, 2022 at 10:26 vote accept Matteo Menghini
Oct 10, 2022 at 22:41 history edited GiorgioP-DoomsdayClockIsAt-90 CC BY-SA 4.0
added a sentence to add another argument to the usefulness of a definition of heat not explicitly based on differences of temperatures.
Oct 10, 2022 at 20:37 history answered GiorgioP-DoomsdayClockIsAt-90 CC BY-SA 4.0