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Jun 17, 2022 at 0:15 comment added Níckolas Alves @AndersGustafson There has to be a mistake in your calculations. While I'm not willing to open the computation in cylindrical coordinates (it will take more time than I have available), I edited the answer to include the examples of spherical and Cartesian separation of variables, since I found the computations readily available on Wikipedia and Weinberg's book. The degeneracy at level $n$ should be $\frac{(n+1)(n+2)}{2}$ regardless of the coordinate system you use when separating variables
Jun 17, 2022 at 0:13 history edited Níckolas Alves CC BY-SA 4.0
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Jun 16, 2022 at 23:24 comment added Anders Gustafson From this I calculated the number of combinations of (n,k,m) to be greater than the number of combinations of (n,l,m) for $n\geq{1}$
Jun 16, 2022 at 23:23 comment added Anders Gustafson I found that it seems that the Energy Levels are the same for spherical and cylindrical coordinates, but in spherical coordinates using $n\geq{0}$, when n is even l can be any even number between 0 and n, and if n is odd l can be any odd number between 1 and n. I found that for cylindrical coordinates if I use k instead of l, with $k\geq{0}$, then if k is even m can be any even number between -k and k, and if k is odd m can be any odd number between -k and k. I found that k can be any integer between 0 and k.
Jun 16, 2022 at 23:20 comment added Anders Gustafson I tried using separation of variables, in spherical and cylindrical coordinates, and then since I know the eigenvalues for both the Colatitude and the Azimuthal Equations, and how they relate to each other, I used the shooting method to find the eigenvalues for the Radial Equation in spherical Coordinates, and the $\rho$, and z equations in cylindrical coordinates, as well as how the eigenvalues of Radial Equation and Colatitude Equation relate to each other in, and how the eigenvalues of the Azimuthal Equation and $\rho$ equation, and the z and $\rho$ equation relate to each other.
Jun 16, 2022 at 23:18 comment added Anders Gustafson I looked up degeneracy and from what I read it looks like in QM degeneracy refers to the number of numbers relating to the shape of the wave function, so for instance for a hydrogen atom when n=2 the energy degeneracy is 4 as the possible combinations of (n,l,m) are (2,0,0), (2,1,0), (2,1,1), and (2,1,-1).
Jun 14, 2022 at 8:08 comment added Níckolas Alves If by "number of configurations" you mean, e.g., the degeneracy of each energy eigenvalue, then yes, all coordinate systems will yield the very same degeneracies
Jun 14, 2022 at 8:07 comment added Níckolas Alves @AndersGustafson I'm not sure I understand what you mean by "same number of configurations". About the energy levels, yes, you'll find the very same energy levels, although the energy eigenstates might be a bit different. For example, in spherical coordinates they are also angular momentum eigenstates, but in Cartesian coordinates they are not. This just means that, in each energy eingenspace, you're choosing a different basis in each coordinate system
Jun 14, 2022 at 4:58 comment added Anders Gustafson Does this just mean that I should find the same Energy Levels with each coordinate system or does it also mean that I should find the same number of configurations in using each coordinate system?
Jun 13, 2022 at 12:37 comment added Níckolas Alves @AndersGustafson Exactly.
Jun 13, 2022 at 3:51 comment added Anders Gustafson So should you find the same states from separation of variables in each coordinate system, but just expressed differently?
Jun 11, 2022 at 20:44 history answered Níckolas Alves CC BY-SA 4.0