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May 8, 2022 at 21:02 comment added bananenheld Thank you for your answer @chemomechanics. So just like a pressure differential 'pushes out' a volume $\Delta V$, a temperature differential 'pushes out' an entropy $\Delta S$. In a certain sense the differentials create a new 'space' for the particles to move. Where as pressure literal space, and temperature new 'energy' states to reach. An irreversible path creates entropy but doesn't create volume is the biggest difference if I understand correctly
May 8, 2022 at 20:57 vote accept bananenheld
May 1, 2022 at 21:16 comment added Chemomechanics Good point; edited to make the context clear.
May 1, 2022 at 21:15 history edited Chemomechanics CC BY-SA 4.0
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May 1, 2022 at 20:56 comment added Kregnach Can I disagree with your last sentence? In classical thermodynamics of gases and regular stuff maybe it's true, but in case of cosmology, especially inflationary models it doesn't hold. If you don't work in flat spacetime that dV becomes really interesting. Fluctuating spacetime generates dV, as fluctuating quantum fields can create particles or entropy. But Its just a comment to your last sentence, your writing is up voted! :)
May 1, 2022 at 16:17 history answered Chemomechanics CC BY-SA 4.0