But today when I try to read some papers working with Alkaline atom, I couldn't figure out how they plot the Rubidium energy level. From my undergraduate study, I thought the diagram of Rubidium atom should be something like this, the outer layer electron is on the energy level of $5S$:
The spin up and spin down electrons occupied the energy levels from ground state go upward. But I really cannot figure out how to read the diagrams of ${ }^{87} \mathbf{R b}$ below:
and
and
So my questions are:
- How could the 6S and 7S5P energy levels be occupied?
- What does the subscript $S_{1/2}$ and $P_{3/2}$ means? Does this means spin? But electron should only have spin number $\pm 1$, right?
- What is the F quantum number? It is not the F from the "spdf" orbital notation, right?
- Can anyone draw a diagram of ${ }^{87} \mathbf{R b}$ with all energy levels and the relationship between different quantum numbers?
Thanks for any help!