Timeline for What is the entropy of a system when its volume tends to zero?
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May 8, 2013 at 9:02 | comment | added | gatsu | @LubošMotl: well it wasn't clear what was being fixed during the process. I understodod the question as: "let us consider a system at equilibrium, I can compute its entropy as a function of its state variables, what is the value of this entropy when the volume tends to zero?". I think this is a fair question and that obviously the answer will depend on the volume. | |
May 8, 2013 at 8:58 | history | edited | gatsu | CC BY-SA 3.0 |
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May 8, 2013 at 8:54 | comment | added | Luboš Motl | The entropy not only refuses to decrease to zero, it never decreases (by a macroscopic amount) at all! Not for a picosecond. The second law says not that the entropy doesn't want to drop to zero; it says that it never drops. Compression of a gas is a mundane, allowed thing; a decrease of the entropy is not possible. They're completely different things. | |
May 8, 2013 at 5:58 | history | answered | gatsu | CC BY-SA 3.0 |