I believe the problem is assuming you release the object from rest (or at leasta constant initial velocity) $v_0$ and the only forces acting on it are gravity, friction, and normal force. You are not applying anotheran initial force $F_0$ or initial torque $\tau_0$ to itthe ball at the beginning by hitting the ballit. If you did the physics would change. Their equations seem correct.
The angular velocity $\omega$ is a function of time $t$ so it's changing over time. It is not constant. The angular acceleration $\frac{5g}{2r} \mu_k$$ \alpha = \frac{5g}{2r} \mu_k$ is what's constant. This makes sense cause you would expect a constant torque (in this case caused by the friction force $f$) to give a constant angular acceleration.