" so why must the wave function for a hydrogen atom be an eigenfunction for πΏΜ^2$\hat{L}^2$ and πΏΜ_π§$\hat{L}_z$?" They must not, but since the H$\hat{H}$, L^2$\hat{L}^2$, L_z$\hat{L}_z$ do commute with each other, they can have some mutual eigenfunctions.You do not have to choose these specific mutual eigenfunctions, you can choose some others, but I think it is obviously very convenient to work with such functions that are simultaneously eigenfunctions of all these three operators(and this is why people usually choose these ones).
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